246137-20-2

Basic information

• Product Name: (3aR,4S,6aR)-6-(Benzyloxymethyl)-4-(triisopropylsilyloxy)-2,2-dimethyl-4,6a-dihydro-3aH-cyclopenta[d][1,3]dioxol
• Synonyms: (3aR,4S,6aR)-6-(Benzyloxymethyl)-4-(triisopropylsilyloxy)-2,2-dimethyl-4,6a-dihydro-3aH-cyclopenta[d][1,3]dioxol
• CAS NO: 246137-20-2
• Molecular Weight: 432.676
• Mol File: 246137-20-2.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: (3aR,4S,6aR)-6-(Benzyloxymethyl)-4-(triisopropylsilyloxy)-2,2-dimethyl-4,6a-dihydro-3aH-cyclopenta[d][1,3]dioxol(CAS DataBase Reference)
• NIST Chemistry Reference: (3aR,4S,6aR)-6-(Benzyloxymethyl)-4-(triisopropylsilyloxy)-2,2-dimethyl-4,6a-dihydro-3aH-cyclopenta[d][1,3]dioxol(246137-20-2)
• EPA Substance Registry System: (3aR,4S,6aR)-6-(Benzyloxymethyl)-4-(triisopropylsilyloxy)-2,2-dimethyl-4,6a-dihydro-3aH-cyclopenta[d][1,3]dioxol(246137-20-2)

Safety Data

• Hazardous Substances Data: 246137-20-2(Hazardous Substances Data)

Upstream product

• 117307-62-7 (3aR,6aR)-6-Benzyloxymethyl-2,2-dimethyl-4,6a-dihydro-3aH-cyclopenta[d][1,3]dioxol-4-one 
• 13154-24-0 triisopropylsilyl chloride 
• 89291-76-9 (1S,4R,5S)-(-)-3-<(benzyloxy)methyl>-4,5-O-isopropylidene-2-cyclopenten-1-ol 

Downstream Products

• 243462-53-5 (4aS)-4,4a-Anhydro-5-O-benzyl-4a-carba-1-O-(triisopropylsilyl)-2,3-O-isopropylidene-β-L-lyxofuranose 

Relevant articles and documents

Chiral pool synthesis of 4a-substituted carbocyclic cyclopentanoid nucleoside precursors, I

A suitable protected D-ribono-1,4-lactone derivative has been used for the straightforward chiral pool synthesis of cyclopentanoid nucleoside precursors. Thus, epoxidation followed by deoxygenation or regioselective ring opening led to nucleoside precurso