24658-23-9

Basic information

• Product Name: (4-methoxyphenyl)(methyl)sulfane-d₃
• Synonyms: (4-methoxyphenyl)(methyl)sulfane-d₃
• CAS NO: 24658-23-9
• Molecular Weight: 157.209
• Mol File: 24658-23-9.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: (4-methoxyphenyl)(methyl)sulfane-d₃(CAS DataBase Reference)
• NIST Chemistry Reference: (4-methoxyphenyl)(methyl)sulfane-d₃(24658-23-9)
• EPA Substance Registry System: (4-methoxyphenyl)(methyl)sulfane-d₃(24658-23-9)

Safety Data

• Hazardous Substances Data: 24658-23-9(Hazardous Substances Data)

Upstream product

• 459-64-3 4-methoxybenzenediazonium tetrafluoroborate 
• 2206-27-1 dimethylsulfoxide-d6 
• 624-92-0 Dimethyldisulphide 
• 696-62-8 para-iodoanisole 

Downstream Products

• 1879-16-9 1-methoxy-4-methylsulfanyl-benzene 

Relevant articles and documents

Visible-light-promoted cross-coupling reactions of aryldiazonium salts with S-methyl-D3 sulfonothioate or Se-methyl-D3 selenium sulfonate: Synthesis of trideuteromethylated sulfides, sulfoxides, and selenides

A novel visible-light-photocatalytic deuterated thiomethylation/methylselenation of aryldiazonium salts utilizing S/ Se-methyl-d3 sulfonothioate has been developed. The mild conditions and the various functional groups provide a green protocol for the efficient and rapid introduction of the S-CD3 or Se-CD3 group with useful levels of deuterium content (>91% D). Trideuteromethyl sulfoxides have also been successfully chemoselectively observed by simple atmospheric changes under photocatalytic conditions.

Copper-mediated methylthiolation of aryl halides with DMSO

A copper-mediated methylthiolation of aryl halides with the widely available DMSO is described. The procedure tolerates a series of functional groups such as methoxy, nitro, chloro, fluoro, trifluoromethyl, formyl and methoxycarbonyl groups. Thus, it represents a simple and facile methylthiolation procedure.