2467-07-4

Basic information

• Product Name: Benzenemethanol, 3,3'-methylenebis[5-(1,1-dimethylethyl)-2-hydroxy-
• CAS NO: 2467-07-4
• Molecular Formula: C23H32O4
• Molecular Weight: 372.505
• Mol File: 2467-07-4.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: Benzenemethanol, 3,3'-methylenebis[5-(1,1-dimethylethyl)-2-hydroxy-(CAS DataBase Reference)
• NIST Chemistry Reference: Benzenemethanol, 3,3'-methylenebis[5-(1,1-dimethylethyl)-2-hydroxy-(2467-07-4)
• EPA Substance Registry System: Benzenemethanol, 3,3'-methylenebis[5-(1,1-dimethylethyl)-2-hydroxy-(2467-07-4)

Safety Data

• Hazardous Substances Data: 2467-07-4(Hazardous Substances Data)

Usage

Function

Antioxidant

Main Uses

1. Prevents spoilage and rancidity in food and cosmetics.
2. Used as an antioxidant in rubber, electrical transformer oil, and jet fuels.
3. Treatment of herpes simplex and other viral infections.

Controversy

Associated with safety concerns and potential health risks at high doses.

Toxicity

High doses linked to possible toxicity and adverse effects.

Upstream product

• 50-00-0 formaldehyd 
• 35851-06-0 3-(5-tert-Butylsalicyl)-5-tert-butyl-2-hydroxybenzyl Alcohol 
• 2203-14-7 4-tert-butyl-2,5-bis(hydroxymethyl)phenol 
• 98-54-4 para-tert-butylphenol 
• 799-13-3 bis(5-tert-butyl-2-hydroxyphenyl)methane 
• 6638-87-5 4-(tert-butyl)-2-(hydroxymethyl)phenol 
• 2725-53-3 2-hydroxy-5-t-butylbenzaldehyde 

Downstream Products

• 992-52-9 2-<3-<3-(5-tert-Butylsalicyl)-5-tert-butylsalicyl>-5-tert-butylsalicyl>-4-tert-butylphenol 
• 475197-29-6 5-tertbutyl-3-[(5-tert-butyl)-2-hydroxy-3-(2-oxovinyl)benzyl]-2-hydroxybenz-aldehyde 
• 847202-26-0 2,2'-bis(allyloxy)-5,5'-di-tert-butyl-3,3'-methanediyldibenzenemathanol 
• 215813-79-9 Bis(5-tert-butyl-3-hydroxymethyl-2-methoxyphenyl)methane 
• 72251-68-4 7,13,19,25-tetra-tert-butyl-2,3-dihomo-3-oxacalix[4]arene 
• 85097-23-0 7,13,21,27-tetra-tert-butyl-29,30,31,32-tetrahydroxy-2,3,16,17-tetrahomo-3,17-dioxacalix<4>arene 
• 123765-91-3 C₄₃H₅₆O₄*2C₆H₁₂ 
• 182946-02-7 2-(3-chloromethyl-2-hydroxy-5-tert-butylbenzyl)-6-chloromethyl-4-tert-butylphenol 
• 1756-93-0 bis-{5-tert-butyl-3-[5-tert-butyl-3-(5-tert-butyl-2-hydroxy-benzyl)-2-hydroxy-benzyl]-2-hydroxy-phenyl}-methane 
• 86952-82-1 bis-(5-tert-butyl-3-{5-tert-butyl-3-[5-tert-butyl-3-(5-tert-butyl-2-hydroxy-benzyl)-2-hydroxy-benzyl]-2-hydroxy-benzyl}-2-hydroxy-phenyl)-methane 

Relevant articles and documents

Synthesis of Monofunctionalized Calix[5]arenes

Seven OH-free and O -permethylated monofunctionalized calix[5]arenes carrying either additional methyl or tert -butyl groups are prepared following fragment condensation protocols. This strategy proves to be superior to previous approaches. Calix[5]arenes with free OH groups all adopt a cone conformation stabilized by a seam of hydrogen bonds at the lower rim. Post-condensation modifications, i.e., methylation of phenolic OH groups or functional group interconversions can also be achieved. Bulky tert -butyl groups are also found to stabilize the cone conformations of O -methylated compounds. These compounds offer versatile functional groups that make these concave molecules interesting building blocks for the synthesis of more sophisticated molecular architectures.

Calixarenes. 10. Oxacalixarenes

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