24672-87-5

Basic information

• Product Name: 4-methoxy-2-(2-methoxy-2-oxoethyl)benzoic acid
• Synonyms: 4-methoxy-2-(2-methoxy-2-oxoethyl)benzoic acid
• CAS NO: 24672-87-5
• Molecular Weight: 224.213
• Mol File: 24672-87-5.mol
• Article Data: 4

Chemical Properties

• CAS DataBase Reference: 4-methoxy-2-(2-methoxy-2-oxoethyl)benzoic acid(CAS DataBase Reference)
• NIST Chemistry Reference: 4-methoxy-2-(2-methoxy-2-oxoethyl)benzoic acid(24672-87-5)
• EPA Substance Registry System: 4-methoxy-2-(2-methoxy-2-oxoethyl)benzoic acid(24672-87-5)

Safety Data

• Hazardous Substances Data: 24672-87-5(Hazardous Substances Data)

Upstream product

• 67-56-1 methanol 
• 105246-90-0 6-methoxyhomophthalic acid anhydride 
• 68294-03-1 2-(carboxymethyl)-4-methoxybenzoic acid 

Downstream Products

• 43088-72-8 6-Methoxyisochroman-3-one 
• 173465-34-4 2-<5-Methoxy-2-(N-methyl-N-pent-4-enylaminocarbonyl)phenyl>-2-diazoacetic acid methyl ester 
• 173465-33-3 <5-Methoxy-2-(N-methyl-N-pent-4-enylaminocarbonyl)phenyl>acetic acid methyl ester 
• 221133-91-1 4-Methoxy-2-methoxycarbonylmethylbenzoic acid 2-oxo-1,2-dihydropyridin-1-yl ester 

Relevant articles and documents

Intramolecular cycloadditions with isobenzofurans - X. A novel synthesis of annulated hydroquinolines

The intramolecular Diels-Alder reaction of 1-amino substituted isobenzofuran 3 leads to hydrobenzo[h] quinolines (5,6).

Intramolecular cycloadditions with 1-aminoisobenzofurans: a simple entry into the field of polycyclic aza-compounds

Starting with 6-methoxyisochromane-1,3-dione (1) isobenzofuran 5 was generated in situ using the Hamaguchi-Ibata methodology. Intramolecular cycloaddition with subsequent transformations provides benzoquinolines of type 7, 8 and 9. In a similar manner 11-azasteroid analogues (22-26) were obtained, starting with 1 and amine 18. Density functional theoretical (DFT) studies of various inter- and intramolecular Diels-Alder reactions are reported.