24696-71-7

Basic information

• Product Name: TETRAPHENYLANTIMONY(V) ACETATE 98
• Synonyms: TETRAPHENYLANTIMONY(V) ACETATE 98;tetraphenylantimony(v) acetate
• CAS NO: 24696-71-7
• Molecular Formula: C₂₆H₂₃O₂Sb
• Molecular Weight: 489.22
• Mol File: 24696-71-7.mol
• Article Data: 1

Chemical Properties

• Melting Point: 120-133 °C(lit.)
• Appearance: /
• CAS DataBase Reference: TETRAPHENYLANTIMONY(V) ACETATE 98(CAS DataBase Reference)
• NIST Chemistry Reference: TETRAPHENYLANTIMONY(V) ACETATE 98(24696-71-7)
• EPA Substance Registry System: TETRAPHENYLANTIMONY(V) ACETATE 98(24696-71-7)

Safety Data

• Hazard Codes: Xn,N
• Statements: 20/22-51/53
• Safety Statements: 61
• RIDADR: UN 3077 9/PG 3
• WGK Germany: 2
• Hazardous Substances Data: 24696-71-7(Hazardous Substances Data)

Downstream Products

• 103-26-4 Methyl cinnamate 
• 603-36-1 triphenylantimony 
• 103-26-4 methyl cinnamate 
• 4096-20-2 N-phenyl piperidine 
• 92-53-5 4-Phenylmorpholine 
• 3297-76-5 1-phenyl-1,2,3,4-tetrahydroquinoline 
• 588-47-6 N-isobutylaniline 
• 1821-36-9 N-phenyl-2-cyclohexylamine 
• 620-84-8 4-methyldiphenylamine 
• 1205-71-6 N-(4-chlorophenyl)aniline 
• 1208-86-2 N-(4-methoxyphenyl)phenylamine 
• 836-30-6 4-ntrophenyl(phenyl)amine 
• 122-39-4 diphenylamine 
• 4058-04-2 N-phenyl-2,6-dimethylaniline 

Relevant articles and documents

Catalytic C-phenylation of methyl acrylate with tetraphenylantimony(v) halides and carboxylates

Catalytic C-phenylation of methyl acrylate to methyl cinnamate with the Ph4SbX complexes (X = F, Cl, Br, OH, OAc, O2CEt) in the presence of the palladium compounds PdCl2, Pd(OAc)2, Pd2(dba)3, Pd(Ph3P)2Cl2, and Pd(dppf)Cl2 (dba is dibenzylideneacetone and dppf is bis(diphenylphosphinoferrocene)) was studied in organic solvents (MeCN, THF, DMF, MeOH, and AcOH). The highest yield of methyl cinnamate (73% based on the starting organometallic compound) was obtained for the Ph4SbCl- PdCl2 (1:0.04) system in acetonitrile.