247113-56-0

Basic information

• Product Name: 2,5-bis[(2-thienyl)(triphenylphosphoranylidene)acetyl]thiophene
• CAS NO: 247113-56-0
• Molecular Weight: 853.018
• Mol File: 247113-56-0.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 2,5-bis[(2-thienyl)(triphenylphosphoranylidene)acetyl]thiophene(CAS DataBase Reference)
• NIST Chemistry Reference: 2,5-bis[(2-thienyl)(triphenylphosphoranylidene)acetyl]thiophene(247113-56-0)
• EPA Substance Registry System: 2,5-bis[(2-thienyl)(triphenylphosphoranylidene)acetyl]thiophene(247113-56-0)

Safety Data

• Hazardous Substances Data: 247113-56-0(Hazardous Substances Data)

Upstream product

• 4282-31-9 Thiophene-2,5-dicarboxylic acid 
• 3857-36-1 thiophene-2,5-dicarbonyl dichloride 
• 23259-98-5 2-thienylmethyltriphenylphosphonium bromide 

Downstream Products

• 53304-21-5 4,4’-bis(2-phenylethynyl)-1,1’-biphenyl 

Relevant articles and documents

Flash vacuum pyrolysis of stabilised phosphorus ylides. Part 16. Model studies for the construction of conjugated polymers

Reaction of a range of bis(ylides) with acid chlorides has been used to prepare the bis(oxoylides) 11-15. Similarly a range of simple ylides react with bis(acid chlorides) to give bis(oxoylides) 19-27 with the isomeric structure. Flash vacuum pyrolysis (FVP) of one example of the first type results in extrusion of Ph3P rather than the expected Ph3PO while six examples of the second type do extrude Ph3PO upon FVP at 500 °C to afford the bis(alkynes) 28. Examples of the corresponding bis(tributylphosphonium ylides) have also been prepared but attempts to construct a tetrakis(oxoylide) 31 using a stepwise approach were unsuccessful. Fully assigned 13C NMR spectra are presented for six of the bis(oxoylides).