24767-67-7

Basic information

• Product Name: 2-Butanone, 3-chloro-1-phenyl-
• CAS NO: 24767-67-7
• Molecular Formula: C10H11ClO
• Molecular Weight: 182.65
• Mol File: 24767-67-7.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: 2-Butanone, 3-chloro-1-phenyl-(CAS DataBase Reference)
• NIST Chemistry Reference: 2-Butanone, 3-chloro-1-phenyl-(24767-67-7)
• EPA Substance Registry System: 2-Butanone, 3-chloro-1-phenyl-(24767-67-7)

Safety Data

• Hazardous Substances Data: 24767-67-7(Hazardous Substances Data)

Upstream product

• 701-70-2 1-phenyl-2-butanol 
• 1560-06-1 1-phenyl-2-butene 
• 6052-66-0 1-phenyl-3-buten-2-ol 
• 99512-23-9 (E)-4-phenyl-3-buten-2-⁽²⁾H-2-ol 

Downstream Products

• 78156-61-3 1-methyl-2-benzylnaphtho<2,1-b>furan 
• 78156-62-4 1-phenyl-2-ethylnaphtho<2,1-b>furan 
• 103-82-2 phenylacetic acid 
• 78156-65-7 1-acetyl-2-phenylacetoxynaphthalene 

Relevant articles and documents

Iridium-catalyzed 1,3-hydrogen shift/chlorination of allylic alcohols

Tandem: Allylic alcohols react with N-chlorosuccinimide (NCS) in a tandem 1,3-H shift/C-Cl bond formation leading to α-chloroketones and α-chloroaldehydes. The reactions proceed with complete selectivity to give single constitutional isomers of monochlorinated carbonyl compounds. The utility of the transformation is illustrated by the straightforward synthesis of 4,5-disubstituted 2-aminothiazoles from allylic alcohols. Copyright

Metal-Catalyzed Organic Photoreactions. One-Step Synthesis of Chlorinated Ketones from Olefins by Photooxidation in the Presence of Iron(III) Chloride

Under photooxidation in pyridine in the presence of FeCl3, mono- and disubstituted olefins gave α-chloro ketones, while tri- and tetrasubstituted olefins gave dichloro ketones with a C-C bond cleavage.The reaction was interpreted in terms of an electron-transfer mechanism occurring within the coordination sphere of the iron ion