249894-62-0

Basic information

• Product Name: 3-Phenyl-5-propyl-1,2,4-trioxolane
• Synonyms: 3-Phenyl-5-propyl-1,2,4-trioxolane
• CAS NO: 249894-62-0
• Molecular Weight: 194.23
• Mol File: 249894-62-0.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: 3-Phenyl-5-propyl-1,2,4-trioxolane(CAS DataBase Reference)
• NIST Chemistry Reference: 3-Phenyl-5-propyl-1,2,4-trioxolane(249894-62-0)
• EPA Substance Registry System: 3-Phenyl-5-propyl-1,2,4-trioxolane(249894-62-0)

Safety Data

• Hazardous Substances Data: 249894-62-0(Hazardous Substances Data)

Upstream product

• 7642-18-4 (Z)-pent-1-en-1-ylbenzene 
• 826-18-6 1-pentenylbenzene 

Downstream Products

• 80735-94-0 1-Phenyl-3-buten-1-ol 
• 100-52-7 benzaldehyde 

Relevant articles and documents

Selectivity in Lewis acid-mediated fragmentations of peroxides and ozonides: Application to the synthesis of alkenes, homoallyl ethers, and 1,2-dioxolanes

Fragmentation of dialkyl peroxides and ozonides is strongly influenced by the choice of Lewis acid. TiCl4 promotes C-O ionization (SN1 reaction) of tertiary peroxides while SnCl4 and BF3·OEt2 promote O-O heterolysis (Hock reaction). The cationic intermediates are trapped with allyltrimethylsilane to afford allylated alkanes and homoallyl ethers. In the absence of a nucleophile, ozonides (1,2,4-trioxolanes) invariably undergo O-O heterolysis. However, the combination of allyltrimethylsilane and SnCl4 results in formation of 1,2-dioxolanes via trapping of intermediates derived from SN1 ionization.