250-21-5Relevant articles and documents
Salomon,Kochi
, p. 2529 (1973)
Srinivasan
, p. 3048 (1963)
Srinivasan
, p. 819 (1963)
Haller,Srinivasan
, p. 5084 (1966)
Photolysis of Some 1-Substituted Cycloocta-1,5-dienes: Synthesis of 1-Fluorotricyclo2,6>octane
Cotsaris, Evangelo,Della, Ernest W.
, p. 2561 - 2564 (2007/10/02)
A study of the photolytic behaviour of several derivatives of cycloocta-1,5-diene as possible precursors of bridgehead-substituted tricyclo2,6>octanes is described.Of the substrates examined, only 1-fluorocycloocta-1,5-diene succesfully underwent photocyclization giving 1-fluorotricyclo2,6>octane. 1-Bromocycloocta-1,5-diene suffered fission of the carbon-bromine bond, while cycloocta-1,5-diene-1-carbonitrile afforded a mixture of at least four unsaturated isomers.