250229-74-4

Basic information

• Product Name: (2R,6R,10R)-1-tert-butyldiphenylsilyloxy-2,6,10-trimethyldodecane
• Synonyms: (2R,6R,10R)-1-tert-butyldiphenylsilyloxy-2,6,10-trimethyldodecane
• CAS NO: 250229-74-4
• Molecular Weight: 466.823
• Mol File: 250229-74-4.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: (2R,6R,10R)-1-tert-butyldiphenylsilyloxy-2,6,10-trimethyldodecane(CAS DataBase Reference)
• NIST Chemistry Reference: (2R,6R,10R)-1-tert-butyldiphenylsilyloxy-2,6,10-trimethyldodecane(250229-74-4)
• EPA Substance Registry System: (2R,6R,10R)-1-tert-butyldiphenylsilyloxy-2,6,10-trimethyldodecane(250229-74-4)

Safety Data

• Hazardous Substances Data: 250229-74-4(Hazardous Substances Data)

Upstream product

• 250229-62-0 (2S,6R)-1-acetoxy-7-tert-butyldiphenylsilyloxy-2,6-dimethylheptane 
• 250229-60-8 (R)-3-methylpentanenitrile 
• 173690-81-8 (2R,6S)-7-acetoxy-2,6-dimethyl-1-heptanol 
• 101382-88-1 (2S,6R)-7-tert-butyldiphenylsilyloxy-2,6-dimethyl-1-heptanol 
• 46481-05-4 (R)-2-methyl-1-butanol 4-methylbenzenesulfonate 
• 70200-36-1 (R)-3-methylpentan-1-ol tosyl ester 
• 40325-99-3 2,6-dimethyl-1,7-heptanediol 
• 16958-25-1 (R)-3-methylpentanoic acid 
• 70224-28-1 (R)-(-)-3-methyl-1-pentanol 
• 616-16-0 (R)-2-Methyl-1-butanol 
• 90410-57-4 (R)-(-)-3-methylpentyl-bromide 
• 250229-73-3 (2S,6R)-7-tert-butyldiphenylsilyloxy-2,6-dimethylheptyl tosylate 

Relevant articles and documents

Pheromone synthesis, CXCVIII. Synthesis of (1S,2S,6S,10R)- and (1S,2R,6R,10R)-1,2,6,10-tetramethyldodecyl propanoate, the components of the sex pheromone of the pine sawfly, Microdiprion pallipes

(1S,2S,6S,10R)- and (1S,2R,6R,10R)-1,2,6,10-tetramethyldodecyl propanoate (1 and 2), the components of the pheromone of Microdiprion pallipes, were synthesized from two chiral and nonracemic building blocks, (R)-3-tert-butoxycarbonyl-2-methylpropanoic acid (D) and (2R,6S)-7-acetoxy- 2,6-dimethyl-1-heptanol (G), by employing lipase-catalyzed kinetic resolution in a later step.