250687-57-1

Basic information

• Product Name: methyl 2,3-di-O-benzyl-4-O-crotonyl-6-O-pivaloyl-α-D-glucopyranoside
• Synonyms: methyl 2,3-di-O-benzyl-4-O-crotonyl-6-O-pivaloyl-α-D-glucopyranoside
• CAS NO: 250687-57-1
• Molecular Weight: 526.627
• Mol File: 250687-57-1.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: methyl 2,3-di-O-benzyl-4-O-crotonyl-6-O-pivaloyl-α-D-glucopyranoside(CAS DataBase Reference)
• NIST Chemistry Reference: methyl 2,3-di-O-benzyl-4-O-crotonyl-6-O-pivaloyl-α-D-glucopyranoside(250687-57-1)
• EPA Substance Registry System: methyl 2,3-di-O-benzyl-4-O-crotonyl-6-O-pivaloyl-α-D-glucopyranoside(250687-57-1)

Safety Data

• Hazardous Substances Data: 250687-57-1(Hazardous Substances Data)

Upstream product

• 623-68-7 trans-crotonic anhydride 
• 184715-41-1 methyl 2,3-di-O-benzyl-6-O-pivaloyl-α-D-glucopyranoside 
• 3282-30-2 pivaloyl chloride 
• 17791-36-5 methyl 2,3-di-O-benzyl-α-D-glucopyranoside 

Relevant articles and documents

Highly diastereoselective 1,4-addition of an organocuprate to methyl α-D-gluco-, α-D-manno-, or α-D-galactopyranosides tethering an α,β-unsaturated ester. Novel asymmetric access to β-C-substituted butanoic acids

The 1,4-addition of magnesium divinylcuprate prepared from vinylmagnesium bromide and cuprous bromide to some 4-O-crotonyl derivatives of methyl α-D-glucopyranoside proceeds with a high level of diastereochemical induction, providing the adduct in good-to