25108-57-0

Basic information

• Product Name: Benzene, 1-methoxy-3-(1-methylethenyl)-
• CAS NO: 25108-57-0
• Molecular Formula: C10H12O
• Molecular Weight: 148.205
• Mol File: 25108-57-0.mol
• Article Data: 33

Chemical Properties

• CAS DataBase Reference: Benzene, 1-methoxy-3-(1-methylethenyl)-(CAS DataBase Reference)
• NIST Chemistry Reference: Benzene, 1-methoxy-3-(1-methylethenyl)-(25108-57-0)
• EPA Substance Registry System: Benzene, 1-methoxy-3-(1-methylethenyl)-(25108-57-0)

Safety Data

• Hazardous Substances Data: 25108-57-0(Hazardous Substances Data)

Upstream product

• 917-64-6 methyl magnesium iodide 
• 586-37-8 1-(3-Methoxyphenyl)ethanone 
• 75-24-1 trimethylaluminum 
• 19493-09-5 Methylenetriphenylphosphorane 
• 55311-42-7 2-(3-methoxyphenyl)propan-2-ol 
• 10035-10-6 hydrogen bromide 
• 71-43-2 benzene 
• 10259-22-0 ethyl 3-methoxybenzoate 
• 2065-66-9 methyl-triphenylphosphonium iodide 
• 1206451-02-6 2-(2-bromo-5-methoxyphenyl)-2-methylpropanal 
• 7765-97-1 meta-hydroxy-α,α-dimethylbenzyl alcohol 
• 51985-05-8 acetic acid-(3-isopropenyl-phenyl ester) 
• 18107-18-1 diazomethyl-trimethyl-silane 
• 108-22-5 Isopropenyl acetate 

Downstream Products

• 860589-95-3 [1-(3-methoxy-phenyl)-1-methyl-ethyl]-dimethyl-amine 
• 1029124-39-7 (E)-1-methoxy-3-(1-nitroprop-1-en-2-yl)benzene 
• 1415643-28-5 1-methoxy-3-(3-tosylprop-1-en-2-yl)benzene 
• 1029124-45-5 (R)-1-methoxy-3-(1-nitropropan-2-yl)benzene 

Relevant articles and documents

1,3-Difunctionalization of β-alkyl nitroalkenes via combination of Lewis base catalysis and radical oxidation

Upon treatment with a Lewis base catalyst, β-alkyl-substituted nitroalkenes could be readily converted into allylic nitro compounds. Examples of either C-1 or C-3 functionalization methods have been reported through nitro-elimination, giving alkene products. In this work, successful 1,3-difunctionalization was achieved through a synergetic Lewis base catalysis and TBHP radical oxidation, giving vinylic alkoxyamines in good to excellent yields. This work further extended the general synthetic application of β-alkyl nitroalkenes.

Visible-light-promoted radical alkylation/cyclization of allylic amide with N-hydroxyphthalimide ester: Synthesis of oxazolines

An efficient photocatalytic alkylation/cyclization of allylic amide with N-hydroxyphthalimide ester has been developed. The transformation is taken advantage of alkyl radicals to attack allylic amide with the assist of inexpensive rose bengal as photocatalyst to prepare a series of alkyl substituted oxazolines in moderate to excellent yields. High regioselectivity, operational safety, mild conditions and excellent substrate generality give this protocol broad application prospects.

Construction of Various Bridged Polycyclic Skeletons by Palladium-Catalyzed Dearomatization

A powerful palladium-catalyzed dearomative cyclization was developed that provides facile access to eight types of bridged tetracyclic skeletons bearing various ring sizes and heterocycles. With this method, several skeletons or analogues of natural products, including tubingensin B and dracaenones, were synthesized. Asymmetric dearomative cyclization enables the construction of various enantiomerically enriched bridged polycyclic systems with up to 99 % ee by employing a chiral palladium catalyst.