252857-45-7

Basic information

• Product Name: (2RS,3R,6R)-tetrahydro-3-(N-1-naphthyl)carbamoyloxy-6-ethenyl-2-phenylselenylmethyl-2,6-dimethyl-2H-pyuran
• CAS NO: 252857-45-7
• Molecular Weight: 494.492
• Mol File: 252857-45-7.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: (2RS,3R,6R)-tetrahydro-3-(N-1-naphthyl)carbamoyloxy-6-ethenyl-2-phenylselenylmethyl-2,6-dimethyl-2H-pyuran(CAS DataBase Reference)
• NIST Chemistry Reference: (2RS,3R,6R)-tetrahydro-3-(N-1-naphthyl)carbamoyloxy-6-ethenyl-2-phenylselenylmethyl-2,6-dimethyl-2H-pyuran(252857-45-7)
• EPA Substance Registry System: (2RS,3R,6R)-tetrahydro-3-(N-1-naphthyl)carbamoyloxy-6-ethenyl-2-phenylselenylmethyl-2,6-dimethyl-2H-pyuran(252857-45-7)

Safety Data

• Hazardous Substances Data: 252857-45-7(Hazardous Substances Data)

Upstream product

• 71098-88-9 N-phenylselanylphthalimide 
• 252857-42-4 (3R,6R)-6-(N-1-naphthyl)carbamoyloxy-3,7-dimethylocta-1,7-dien-3-ol 
• 252857-43-5 (3R,6R)-6-acetoxy-3-(N-1-naphthyl)carbamoyloxy-2,6-dimethyloct-7-en-2-ol 
• 252857-44-6 (3R,6R)-6-acetoxy-3-(N-1-naphthyl)carbamoyloxy-2,6-dimethylocta-1,7-diene 
• 185141-68-8 (3R,6R)-6-acetoxy-2,6-dimethyloct-7-en-2,3-diol 
• 16509-46-9 (3R)-3-acetoxy-3,7-dimethylocta-1,6-diene 
• 126-91-0 linalool 

Relevant articles and documents

Enantioselective synthesis of each stereoisomer of the pyranoid linalool oxides: The linalool route

Each of the four enantiomerically pure tetrahydropyran linalool oxides was prepared by separate enantioselective Sharpless dihydroxylation of (R)- or (S)-linalyl acetate with AD-mix-α or AD-mix-β, followed by a completely stereoselective N-phenylselenophthalimide cyclization of an intermediate allylic alcohol.