25315-10-0

Basic information

• Product Name: 1-Bromo-2,6-dimethoxynaphthalene
• Synonyms: 1-Bromo-2,6-dimethoxynaphthalene
• CAS NO: 25315-10-0
• Molecular Formula: C₁₂H₁₁BrO₂
• Molecular Weight: 267.12
• Mol File: 25315-10-0.mol
• Article Data: 3

Chemical Properties

• Appearance: /
• CAS DataBase Reference: 1-Bromo-2,6-dimethoxynaphthalene(CAS DataBase Reference)
• NIST Chemistry Reference: 1-Bromo-2,6-dimethoxynaphthalene(25315-10-0)
• EPA Substance Registry System: 1-Bromo-2,6-dimethoxynaphthalene(25315-10-0)

Safety Data

• Hazardous Substances Data: 25315-10-0(Hazardous Substances Data)

Upstream product

• 5486-55-5 2,6-dimethoxylnaphthalene 

Relevant articles and documents

Construction of Axially Chiral Arylborons via Atroposelective Miyaura Borylation

Compared with the well-developed centrally chiral boron chemistry, C-B axially chiral chemistry remains elusive and challenging. Herein we report the first atroposelective Miyaura borylation of bromoarenes with unsymmetrical diboron reagents for the direct catalytic synthesis of optically active atropisomeric arylborons. This reaction features broad substrate scope and produces axially chiral arylborons with high yields and good enantioselectivities.

Palladium-Catalyzed Enantioselective Synthesis of 2-Aryl Cyclohex-2-enone Atropisomers: Platform Molecules for the Divergent Synthesis of Axially Chiral Biaryl Compounds

The palladium-catalyzed asymmetric synthesis of enone-based atropisomers from 2-iodo-3-methylcyclohex-2-enones and aryl boronic acid is reported. BoPhoz-type phosphine–aminophosphine ligands showed superior enantioselectivity over other ligands. These cyc