25343-67-3

Basic information

• Product Name: Benzene, (1-isothiocyanato-1-methylethyl)-
• CAS NO: 25343-67-3
• Molecular Formula: C10H11NS
• Molecular Weight: 177.27
• Mol File: 25343-67-3.mol
• Article Data: 8

Chemical Properties

• CAS DataBase Reference: Benzene, (1-isothiocyanato-1-methylethyl)-(CAS DataBase Reference)
• NIST Chemistry Reference: Benzene, (1-isothiocyanato-1-methylethyl)-(25343-67-3)
• EPA Substance Registry System: Benzene, (1-isothiocyanato-1-methylethyl)-(25343-67-3)

Safety Data

• Hazardous Substances Data: 25343-67-3(Hazardous Substances Data)

Upstream product

• 7664-93-9 sulfuric acid 
• 540-72-7 sodium thiocyanide 
• 98-83-9 isopropenylbenzene 
• 585-32-0 2-phenyl-2-propylamine 
• 2290-65-5 trimethylsilyl isothiocyanate 
• 29284-59-1 thiocyanogen bromide 
• 617-94-7 1-methyl-1-phenylethyl alcohol 
• 1147550-11-5 ammonium thiocyanate 
• 934-53-2 cumenyl chloride 
• 98-82-8 Isopropylbenzene 
• 5961-98-8 thiocyanatochloride 
• 60245-52-5 (2-iodo-1-isothiocyanato-1-methyl-ethyl)-benzene 
• 56-23-5 tetrachloromethane 
• 505-14-6 thiocyanogen 

Downstream Products

• 66896-49-9 N-methylcumylamine 
• 1401349-50-5 N-(2-phenylpropan-2-yl)-5-(3-(pyrimidin-2-yl)-1-tosyl-1H-indol-5-yl)-1,3,4-oxadiazol-2-amine 
• 95880-21-0 N-(2-phenylpropan-2-yl)hydrazinecarbothioamide 
• 1401349-46-9 5-(3-(6-cyclopropylpyrazin-2-yl)-1-tosyl-1H-indol-5-yl)-N-(2-phenylpropan-2-yl)-1,3,4-oxadiazol-2-amine 
• 1401349-45-8 N-(2-phenylpropan-2-yl)-5-(3-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)-1-tosyl-1H-indol-5-yl)-1,3,4-oxadiazol-2-amine 
• 1401349-44-7 5-(3-iodo-1-tosyl-1H-indol-5-yl)-N-(2-phenylpropan-2-yl)-1,3,4-oxadiazol-2-amine 
• 24053-81-4 N¹,N¹-Diisopropyl-N²-(α,α-dimethyl-benzyl)-formamidin 
• 24053-80-3 N¹,N¹-Dimethyl-N²-(α,α-dimethyl-benzyl)-formamidin 
• 24053-67-6 N¹,N¹-Diisopropyl-N²-(α,α-dimethyl-benzyl)-thioharnstoff 
• 24053-66-5 N,N-dimethyl-N'-(1-methyl-1-phenyl-ethyl)-thiourea 
• 109473-49-6 morpholine-4-carbothioic acid 1-methyl-1-phenyl-ethylamide 
• 32767-63-8 N,N'-bis-(1-methyl-1-phenyl-ethyl)-thiourea 
• 102660-50-4 N-Methyl-N-<2-phenyl-propyl-(2)>-N'-naphthyl-(1)-harnstoff 

Relevant articles and documents

Reaction of Thiocarbonyl Fluoride Generated from Difluorocarbene with Amines

The reaction of thiocarbonyl fluoride, generated from difluorocarbene, with various amines under mild conditions is described. Secondary amines, primary amines, and o-phenylenediamines are converted to thiocarbamoyl fluorides, isothiocyanates, and difluoromethylthiolated heterocycles, respectively. Thiocarbamoyl fluorides were further transformed into trifluoromethylated amines by using a one-pot process. Thiocarbonyl fluoride is generated in situ and is rapidly fully converted in one pot under mild conditions; therefore, no special safety precautions are needed.

Phosphine-free conversion of alcohols into alkyl thiocyanates using trichloroisocyanuric acid/NH4SCN

A convenient and efficient phosphine-free procedure for the one-pot conversion of primary, secondary and tertiary alcohols into the corresponding alkyl thiocyanates or alkyl isothiocyanates is described using trichloroisocyanuric acid/NH4SCN.

Oxalic acid-catalyzed reaction of alcohols with NaSCN: The effects of additives NaI and i2

Oxalic acid-mediated conversion of alcohols to thiocyante and/or isothiocyanate is described. Aliphatic tertiary alcohols give isothiocyanate by the reaction with NaSCN in the presence of I2, whereas they give thiocyanate without it. Copyright