25387-93-3

Basic information

• Product Name: (quinolin-8-olato)lithium
• Synonyms: (Quinolin-8-olato)lithium; lithium quinolin-8-olate
• CAS NO: 25387-93-3
• Molecular Formula: C₉H₆NO*Li
• Molecular Weight: 151.091
• EINECS: 246-932-3
• Mol File: 25387-93-3.mol
• Article Data: 4

Chemical Properties

• Boiling Point: 267°C at 760 mmHg
• Flash Point: 143.1°C
• Vapor Pressure: 0.00508mmHg at 25°C
• CAS DataBase Reference: (quinolin-8-olato)lithium(CAS DataBase Reference)
• NIST Chemistry Reference: (quinolin-8-olato)lithium(25387-93-3)
• EPA Substance Registry System: (quinolin-8-olato)lithium(25387-93-3)

Safety Data

• Hazardous Substances Data: 25387-93-3(Hazardous Substances Data)

Usage

General Description

(Quinolin-8-olato)lithium is a chemical compound composed of a lithium ion bound to a quinolin-8-olato ligand. It is a coordination complex that can be used as a catalyst in organic synthesis reactions, particularly in the formation of carbon-carbon and carbon-heteroatom bonds. (quinolin-8-olato)lithium has been studied for its potential application in asymmetric catalysis, as well as in the preparation of pharmaceutically relevant molecules. It exhibits strong nucleophilic behavior and has been reported to be an effective reagent for the functionalization of organic substrates. Additionally, (quinolin-8-olato)lithium has been investigated for its role in promoting cross-coupling reactions and other important transformations in organic chemistry.

Upstream product

• 148-24-3 8-quinolinol 

Relevant articles and documents

Preparation Method for Lithium Quinolate Nanorod

The present invention relates to a method for manufacturing lithium quinolate and lithium quinolate nanorod crystals, which are stable even for long-term storage and have high yields upon purification by sublimation. More specifically, the present invention relates to the method for manufacturing lithium quinolate comprising steps of: (A) dissolving 8-hydroxyquinoline in a solvent; (B) slowly adding lithium hydride to the solution and stirring the same; and (C) filtering a precipitate from the reaction solution.COPYRIGHT KIPO 2019

LITHIUM METAL QUINOLATES AND PROCESS FOR PREPARATION THEREOF AS GOOD EMITTING, INTERFACE MATERIALS AS WELL AS N-TYPE DOPENT FOR ORGANIC ELECTRONIC DEVICES

Invention relates to a single step preparation of alkali metal quinolate of general formula 1 wherein M=Lithium, sodium or potassium;R═H, alkyl (C1-C6), alkoxy, aryl, aryloxy, amino, amido or halogen (Cl, F, Br, I) which is substituted or unsubstituted with direct reaction of metal with 8-hydroxyquinoline. Substituted 8-hydroxyquinoline optionally have at least one substituent selected from the group consisting of alkyl, alkoxy, aryl, aryloxy, amino, amido at 2, 5 or 7 position. Halogen substituted 8-hydroxyquinolates are also prepared from this method in the yield of 90-95% from polar solvents like acetonitrile. These complexes are useful as light emitting and electron injecting materials in organic electronic devices. Also the doping of these materials in electron transport materials improves their electron mobility.