25445-03-8Relevant articles and documents
Lewis acid-catalyzed, copper(II)-mediated synthesis of heteroaryl thioethers under base-free conditions
Dai, Chao,Xu, Zhaoqing,Huang, Fei,Yu, Zhengkun,Gao, Yan-Feng
experimental part, p. 4414 - 4419 (2012/06/18)
A Lewis acid (AgI, NiII, or FeII) catalyzed, CuII-mediated thiolation reaction between heteroarenes and thiols was achieved with good yield under base-free conditions. DMSO could serve as an effective methylthiolation reagent for the synthesis of heterocyclic methyl thioethers.