25482-26-2

Basic information

• Product Name: 5,10,15,20-tetraphenyl porphyrinato iron hydroxide
• Synonyms: 5,10,15,20-tetraphenyl porphyrinato iron hydroxide
• CAS NO: 25482-26-2
• Molecular Weight: 685.587
• Mol File: 25482-26-2.mol
• Article Data: 5

Chemical Properties

• CAS DataBase Reference: 5,10,15,20-tetraphenyl porphyrinato iron hydroxide(CAS DataBase Reference)
• NIST Chemistry Reference: 5,10,15,20-tetraphenyl porphyrinato iron hydroxide(25482-26-2)
• EPA Substance Registry System: 5,10,15,20-tetraphenyl porphyrinato iron hydroxide(25482-26-2)

Safety Data

• Hazardous Substances Data: 25482-26-2(Hazardous Substances Data)

Upstream product

• 29484-63-7 iron(III) tetraphenylporphyrin 
• 917-23-7 5,10,15,20-tetraphenyl-21H,23H-porphine 
• 1834-30-6 iron(II) acetate 
• 12582-61-5 ((5,10,15,20-tetraphenylporphyrinato)iron(III))2O 
• 16591-56-3 5,10,15,20-tetraphenyl porphyrin iron 
• 16456-81-8 meso-tetraphenylporphyrin iron(III) chloride 
• 1310-73-2 sodium hydroxide 
• 52155-25-6 Fe(tetraphenylporphyrinato)(1-methylimidazole)2⁽¹⁺⁾ 

Downstream Products

• 51455-98-2 azido(tetraphenylporphyrinato)iron(III) 

Relevant articles and documents

Highly selective catalytic preparation of bis(4-oxo-benzo-2-cyclohexen-1-yl) amine from 1-naphthylamine oxidation over metalloporphyrin catalysts by molecular oxygen under air pressure and by hydrogen peroxide

In the presence of molecular oxygen or hydrogen peroxide, 1-naphthylamine (1-NA) was catalytically converted into bis(4-oxo-benzo-2-cyclohexen-1-yl) amine (BOBCHA) over metalloporphyrin catalysts through an oxidative-coupling way. UV-vis, IR, NMR, MS, mp determinations and elemental analysis were employed for product characterization. A possible catalytic mechanism based on in situ UV-vis and EPR determinations was proposed. A spectrophotometric method was established for quantitative analysis of the product according to its characteristic absorption at λmax = 465 nm. The influences of reaction conditions, such as solvents, temperature, reaction time, medium alkalinity, as well as species and amount of the catalysts were discussed in detail.

Hydroxide-induced reduction of (tetraphenylporphinato)iron(III) in pyridine [2]

-

New Five- and Six-Coordinate Imidazole and Imidazolate Complexes of Ferric Tetraphenylporphyrine

The synthesis of several new imidazole and imidazolate complexes of ferric tetraphenylporphyrine (TPP) are reported.The following coplexes have been made with L = imidazole (ImH) or 4-methylimidazole (4MeImH) and L- = imidazolate (Im-) or 4-methylimidazolate (4MeIm-): FeTPP(L)(L-), -2>-, and (SbF6).Addition of Im- to FeTPPCl resulted in the formation first of the imidazolate-bridged complex + and then of -.Similar addition of 4MeIm- to FeTPPCl resulted in the formation first of the high-spin mononuclear complex FeTPP(4MeIm) and then of -.The affinity of (SbF6) for a second 4MeImH was found to be very high, with K >/= 107 M-1 in toluene, 25 deg C.By contrast, 4MeImH was found preferentially to hydrogen bond to Fe(TPP)(4MeIm), with K ca. 5 * 104 M-1 in THF, 25 deg C.Coordination of 4MeImH was only observed at high concentration of ligand (K ca. 50 +/- 10 M-1).The monoimidazole complex (SbF6) was concluded to be high spin after a comparison of the visible spectral properties of a large number of ferric TPP complexes.