25491-50-3

Basic information

• Product Name: Phenol, thallium(1+) salt
• CAS NO: 25491-50-3
• Molecular Formula: C6H6O.Tl
• Molecular Weight: 297.488
• Mol File: 25491-50-3.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: Phenol, thallium(1+) salt(CAS DataBase Reference)
• NIST Chemistry Reference: Phenol, thallium(1+) salt(25491-50-3)
• EPA Substance Registry System: Phenol, thallium(1+) salt(25491-50-3)

Safety Data

• Hazardous Substances Data: 25491-50-3(Hazardous Substances Data)

Upstream product

• 120777-38-0 Tl(2,2'-dipyridylamido) 
• 108-95-2 phenol 
• 20398-06-5 thallium (I) ethoxide 

Downstream Products

• 61817-37-6 hydrido(π-phenoxo)bis(triphenylphosphine)ruthenium(II) 
• 115017-44-2 rhenium(III)(oxo)(phenoxide)bis(t-BuCCH) 
• 115017-43-1 Re(O)(O(C₆H₅))(CH₃CCCH₃)2 
• 72017-13-1 thallous bromoacetate 
• 108-95-2 phenol 
• 118050-16-1 1-Methyl-4-(1-phenoxy-2,3,4,5-tetraphenyl-cyclopenta-2,4-dienyl)-benzene 
• 61133-42-4 3-phenoxy-1,3-dihydro-1-isobenzofuranone 
• 640-60-8 toluene-4-sulfonic acid phenyl ester 
• 4920-92-7 pivalic acid phenyl ester 
• 40193-22-4 Chloro-(3,5,7-trimethyl-adamantan-1-yl)-acetic acid phenyl ester 

Relevant articles and documents

O-Acylation using organothallium compounds

Thallous salts of β-dicarbonyl compounds, prepared by reaction of the β-dicarbonyl compounds with a thallous alkoxide, are treated with alkyl halides to give C-alkyl products in high yield, with acyl halides at room temperature to give C-acyl products, and with acyl halides at low temperatures to give O-acyl products. Thallous phenolates are esterified with acyl or aroyl halides. Anhydrides are also prepared, as are biaryls and bi-sec-alkyls. N-Heterocyclics, including purines and pyrimidines, are N-alkylated. Lactams are O-acylated or N-alkylated.