254973-56-3

Basic information

• Product Name: 2-(4-Chlorophenyl)-2-(trimethylsilyl)-1,3-dithiane
• Synonyms: 2-(4-Chlorophenyl)-2-(trimethylsilyl)-1,3-dithiane
• CAS NO: 254973-56-3
• Molecular Weight: 302.964
• Mol File: 254973-56-3.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: 2-(4-Chlorophenyl)-2-(trimethylsilyl)-1,3-dithiane(CAS DataBase Reference)
• NIST Chemistry Reference: 2-(4-Chlorophenyl)-2-(trimethylsilyl)-1,3-dithiane(254973-56-3)
• EPA Substance Registry System: 2-(4-Chlorophenyl)-2-(trimethylsilyl)-1,3-dithiane(254973-56-3)

Safety Data

• Hazardous Substances Data: 254973-56-3(Hazardous Substances Data)

Upstream product

• 75-77-4 chloro-trimethyl-silane 
• 10359-09-8 2-(4-chlorophenyl)-1,3-dithiane 
• 104-88-1 4-chlorobenzaldehyde 

Downstream Products

• 75748-10-6 trimethyl-4-chlorobenzoylsilane 
• 74-11-3 para-chlorobenzoic acid 

Relevant articles and documents

Oxidative [1,2]-Brook Rearrangements Exploiting Single-Electron Transfer: Photoredox-Catalyzed Alkylations and Arylations

Oxidative [1,2]-Brook rearrangements via hypervalent silicon intermediates induced by photoredox-catalyzed single-electron transfer have been achieved, permitting the formation of reactive radical species that can engage in alkylations and arylations.

Enantioselective synthesis of a-hydroxysilanes by bioreduction of aroyltrimcthylsilanes

Aromatic acylsilanes [Ar-CO-SiMe3; Ar = C6H5,4-ClC6H4, 2-, 3- and 4-OMeC6H4, 3,4-(OMe)2C6H3 and 3,4-OCH2OC6H3] were reduced by baker's yeast to optically active a-silyl alcohols in 20-70% yield and 43-88% ee. Comments are made on the influence of silicon in this bioreduction reaction. The Royal Society of Chemistry 1999.