2550-62-1

Basic information

• Product Name: Methanesulfonic acid, lithium salt
• CAS NO: 2550-62-1
• Molecular Formula: CH4O3S.Li
• Molecular Weight: 102.04
• Mol File: 2550-62-1.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: Methanesulfonic acid, lithium salt(CAS DataBase Reference)
• NIST Chemistry Reference: Methanesulfonic acid, lithium salt(2550-62-1)
• EPA Substance Registry System: Methanesulfonic acid, lithium salt(2550-62-1)

Safety Data

• Hazardous Substances Data: 2550-62-1(Hazardous Substances Data)

Upstream product

• 10307-28-5 1-octanesulfonic acid methyl ester 

Relevant articles and documents

Mechanism and Anion Activation in Solid-Liquid Phase-transfer Reactions Catalysed by Cyclophosphazenic Polypodands. Comparison with Cyclic Analogue Crown Ethers

A kinetic study of the nucleophilic substitution of the methanesulfonic group by anions (Cl-, Br-, I-, SCN-, C6H5O-, C6H5CH2COO-) catalysed by cyclophosphazenic polypodands has been performed under solid-liquid phase-transfer conditions.The results obtained show that the mechanism of PTC previously found for cyclic ligands (crown ethers, cryptands) also operates in the case of these open-chain ligands: the attack by the anionic nucleophile on the substrate occurs in the organic phase and is rate determining of the overall process.The nucleophilicity scales found (I- > C6H5O- ca.SCN- > C6H5CH2COO-; I- > Br- > Cl-) as well as the anion activation are comparable with those found for cyclic crown ethers.This indicates that the anionic reactive species involved are similar in the complexes of both ligands.