25524-42-9

Basic information

• Product Name: (5Z)-5-Tridecene
• Synonyms: (5Z)-5-Tridecene;(Z)-5-Tridecene
• CAS NO: 25524-42-9
• Molecular Formula: C₁₃H₂₆
• Molecular Weight: 182.34554
• Mol File: 25524-42-9.mol
• Article Data: 4

Chemical Properties

• Boiling Point: 232.3°C at 760 mmHg
• Flash Point: 87.2°C
• Appearance: /
• Density: 0.77g/cm³
• Vapor Pressure: 0.0903mmHg at 25°C
• Refractive Index: 1.439
• CAS DataBase Reference: (5Z)-5-Tridecene(CAS DataBase Reference)
• NIST Chemistry Reference: (5Z)-5-Tridecene(25524-42-9)
• EPA Substance Registry System: (5Z)-5-Tridecene(25524-42-9)

Safety Data

• Hazardous Substances Data: 25524-42-9(Hazardous Substances Data)

Usage

InChI:InChI=1/C13H26/c1-3-5-7-9-11-13-12-10-8-6-4-2/h9,11H,3-8,10,12-13H2,1-2H3/b11-9-

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Relevant articles and documents

1-Methyl-1H-tetrazol-5-yl (MT) sulfones in the Julia-Kocienski olefination: Comparison with the PT and the TBT sulfones

The stability and the stereoselectivity of newly prepared n-pentyl 1-methyl-1H-tetrazol-5-yl (MT) sulfone 1a in the Julia-Kocienski reactions were compared with those of the PT sulfone 1b and the TBT sulfone 1c. The improved stability of the anion derived from the n-pentyl MT sulfone 1a enhanced the efficiency of the olefination reactions and gave higher yields of the product alkenes 3 compared with the PT sulfone 1b. Especially high E-selectivity and high yields were obtained from the reaction with aromatic aldehydes and α,β-unsaturated aldehydes. The selectivity of 1a was not so sensitive to the change of base counter ion compared with the PT sulfone 1b. The reaction of the MT sulfones having either ethyl or a longer alkyl chain also gave E-alkenes selectively in high yields.

Tandem application of C-C bond-forming reactions with reductive ozonolysis

Several variants of reductive ozonolysis, defined here as the in situ generation of aldehydes or ketones during ozonolytic cleavage of alkenes, are demonstrated to work effectively in tandem with a number of C-C bond-forming reactions. For reactions involving basic nucleophiles (1,2- addition of Grignard reagents, Wittig or Horner-Emmons olefinations, and directed aldol reactions of lithium enolates), the one-pot process offers a rapid and high-yielding alternative to traditional two-step protocols.