255711-84-3Relevant articles and documents
Rhodium-catalyzed enantioselective hydrogenation of unsaturated phosphonates by ClickFerrophos ligands
Konno, Takashi,Shimizu, Kenta,Ogata, Kenichi,Fukuzawa, Shin-Ichi
, p. 3318 - 3324 (2012)
Newly developed ClickFerrophos II ligands were applied in the hydrogenation of α,β-unsaturated phosphonates. The use of a rhodium/ClickFerrophos II catalyst was examined in the hydrogenation of functionalized α,β-unsaturated phosphonates and was revealed
Inverting External Asymmetric Induction via Selective Energy Transfer Catalysis: A Strategy to β-Chiral Phosphonate Antipodes
Onneken, Carina,Bussmann, Kathrin,Gilmour, Ryan
supporting information, p. 330 - 334 (2019/12/11)
Enantiodivergent, catalytic reduction of activated alkenes relays stereochemical information encoded in the antipodal chiral catalysts to the pro-chiral substrate. Although powerful, the strategy remains vulnerable to costs and availability of sourcing bo
Enantioselective synthesis of optically active alkylphosphonates via Rh-catalyzed asymmetric hydrogenation of β-substituted α,β- unsaturated phosphonates
Duan, Zheng-Chao,Wang, Lian-Zhi,Song, Xin-Jian,Hu, Xiang-Ping,Zheng, Zhuo
scheme or table, p. 508 - 514 (2012/08/07)
The Rh-catalyzed asymmetric hydrogenation of β-substituted α,β-unsaturated phosphonates using (Sc,S p)-WalPhos as the chiral ligand is reported, in which a wide range of optically active β-substituted alkylphosphonates were obtained
