255829-25-5Relevant articles and documents
Synthesis of nitrocarbazole compounds and their electrocatalytic oxidation of alcohol
Zhu, Yinghong,Zhang, Jianqing,Chen, Ziying,Zhang, Anlun,Ma, Chunan
, p. 533 - 538 (2016)
Three compounds with nitrocarbazole frameworks were synthesized and their electrochemical reversibility as organic electrocatalysts was studied by cyclic voltammetry. The electrochemical reversibility and oxidation-reduction potential of the compounds were greatly affected by their substituents. The oxidation-reduction potential of the compound with an electron-donating group was negative, while that of the compound with an electron-withdrawing group on the carbazole framework was positive. The electrocatalytic oxidation activities of the nitrocarbazole compounds were investigated through cyclic voltammetry and controlled potential electrolysis at room temperature. The electrocatalysts showed excellent selectivity for p-methoxybenzyl alcohol, converting it to the corresponding aldehyde through electro-oxidation with just 2.5 mol% of the electrocatalysts presented. The electrocatalysts maintained their excellent electroredox activity following recycling.
Arylamino-functionalized fluorene- and carbazole-based copolymers: Color-tuning their CdTe nanocrystal composites from red to white
Kanelidis, Ioannis,Ren, Yi,Lesnyak, Vladimir,Gasse, Jan-Christoph,Frahm, Ronald,Eychmueller, Alexander,Holder, Elisabeth
experimental part, p. 392 - 402 (2012/01/06)
Four alternating arylamino-functionalized copolymers were synthesized in a Suzuki copolymerization applying 4, 4′-(2,7-dibromo-9H-fluorene-9,9-diyl) dianiline, 4,4′-(2,7-dibromo-9H-fluorene-9,9-diyl)bis(N,N-diphenylaniline) , 4-(3,6-dibromo-9H- carbazol-9
MONOMER OF THE "PUSH-PULL" TYPE AND PHOTOCHROMIC ELECTROCONDUCTING POLYMER MATERIAL OBTAINED FROM THIS MONOMER
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Page/Page column 4, (2008/12/06)
The invention relates to a “push-pull” type compound, used for manufacturing polymer materials having both electrical conduction and photochromic properties, which responds to the general formula A-X-R in which: A is an electron acceptor group;X is a group having a π-conjugated system and forms a photochromic group with A; andR is a polymerizable electron-donor group that is chosen among the carbazole group and the groups derived from the carbazole group by substitution, and which is linked to X by the nitrogen atom of the carbazole group. The invention also relates to an electroconducting and photochromic polymer material, obtained by polymerization of this compound. Applications: optoelectronics, signal processing, data storage, etc.