255829-44-8Relevant articles and documents
π-conjugated aromatic enynes as a single-emitting component for white electroluminescence
Liu, Yu,Nishiura, Masayoshi,Wang, Yue,Hou, Zhaomin
, p. 5592 - 5593 (2006)
By use of the organolanthanide catalysts Me2Si(C5Me4)(NAr)Lu(CH2SiMe3)(THF) and (C5Me5)2LaCH(SiMe3)2, carbazole-substituted phenyl enynes (Z)-CPE
Easily oxidizable triarylamine materials with naphthalene and binaphthalene core: structure–properties relationship
Kerner, Luká?,Gmucová, Katarína,Ko?í?ek, Jozef,Pet?í?ek, Václav,Putala, Martin
, p. 7081 - 7092 (2016/10/14)
We devised and synthesized a series of electron-rich compounds featuring diphenylamine, carbazole or dibenzo[c,g]carbazole connected via phenylacetylene linkers to an aromatic central unit. The key synthetic step was a high yielding cross coupling reaction between halogenated (bi)naphthalene and organometallic reagents prepared in situ from terminal alkynes (side-arms). By masking one of the iodo functions with a diethyltriazenyl group in the side-arm precursors, we efficiently circumvented the formation of doubly aminated by-products. Although one step longer, this approach led to higher yields of terminal alkynes than the direct coupling route. Spectroscopic and electrochemical measurements supported by computational evidence revealed that conjugation in the 1,4-disubstituted naphthalene backbone is superior to the 1,5 or 2,6 substituted cores. The diphenylamine derivative gets oxidized more readily when compared to its carbazole analogs. Expanding the core to binaphthalene did not alter electronic properties, but influenced the physical characteristics significantly.
Synthesis and photochemical properties of 3,6-di-tert-butyl-9H-carbazole derivatives
Gruzdev,Chervonova,Venediktov,Rozhkova,Kolker,Mazaev,Dudina,Domracheva
, p. 1431 - 1439 (2015/08/03)
Method of synthesis has been developed for a series of 3,6-di-tert-butyl-9H-carbazole derivatives and their photochemical properties have been investigated. The dependence of the Steglich esterification reaction on the nature of the catalyst was studied. The synthesized compounds show fluorescent emission in the range 400-600 nm with a high quantum yield.