25722-66-1

Basic information

• Product Name: Cyanic acid (1-methylethylidene)di-4,1-phenylene ester homopolymer
• Synonyms: CYANIC ACID, (1-METHYLETHYLIDENE)DI-4,1-PHENYLENE ESTER, HOMOPOLYMER;PRIMASET BA-230;(1-Methylethylidene)di-4,1-phenylene cyanate homopolymer;2,2-Bis-(4-cyanatophenyl)-propane homopolymer;Cyanic acid, (1-methylidene)di-4,1-phenylene ester
• CAS NO: 25722-66-1
• Molecular Formula: C17H14N2O2
• Molecular Weight: 278.30526
• Product Categories: Hydrocyanic acid derivatives;Cyanates
• Mol File: 25722-66-1.mol
• Article Data: 6

Chemical Properties

• Melting Point: 110°C
• Appearance: /
• CAS DataBase Reference: Cyanic acid (1-methylethylidene)di-4,1-phenylene ester homopolymer(CAS DataBase Reference)
• NIST Chemistry Reference: Cyanic acid (1-methylethylidene)di-4,1-phenylene ester homopolymer(25722-66-1)
• EPA Substance Registry System: Cyanic acid (1-methylethylidene)di-4,1-phenylene ester homopolymer(25722-66-1)

Safety Data

• Hazardous Substances Data: 25722-66-1(Hazardous Substances Data)

Usage

Description

Cyanic acid (1-methylethylidene)di-4,1-phenylene ester homopolymer, also known as PRIMASET(R) BA-230 S, is a prepolymer bisphenol A dicyanate with a solidified melt chemical property. It is supplied at 75% solid in methyl ethyl ketone (MEK) and is characterized by its unique chemical structure and properties.

Uses

Used in Adhesive Industry:
Cyanic acid (1-methylethylidene)di-4,1-phenylene ester homopolymer is used as an adhesive component for its strong bonding capabilities and solidified melt properties, which contribute to the formation of durable and long-lasting adhesives.
Used in Coatings Industry:
In the coatings industry, Cyanic acid (1-methylethylidene)di-4,1-phenylene ester homopolymer is used as a component in the formulation of high-performance coatings. Its solidified melt property and chemical stability provide enhanced durability and resistance to various environmental factors.
Used in Composite Materials:
Cyanic acid (1-methylethylidene)di-4,1-phenylene ester homopolymer is utilized as a reinforcing agent in the development of composite materials. Its unique chemical structure and properties contribute to the enhancement of mechanical strength and thermal stability of the composites.
Used in Plastics Industry:
In the plastics industry, Cyanic acid (1-methylethylidene)di-4,1-phenylene ester homopolymer is used as a modifier to improve the properties of various plastic materials. Its solidified melt property and chemical stability help in achieving better mechanical strength, thermal resistance, and durability in the final plastic products.
Used in Elastomers:
Cyanic acid (1-methylethylidene)di-4,1-phenylene ester homopolymer is employed as a component in the production of elastomers. Its solidified melt property and chemical structure contribute to the development of elastomers with improved mechanical properties and resistance to various environmental factors.

InChI:InChI=1/C17H14N2O2/c1-17(2,13-3-7-15(8-4-13)20-11-18)14-5-9-16(10-6-14)21-12-19/h3-10H,1-2H3

Upstream product

• 80-05-7 BPA 
• 506-77-4 cyanogen chloride 
• 506-68-3 bromocyane 

Downstream Products

• 1110-13-0 2.2-Bis-<4-p-tolylguanyloxy-phenyl>-propan 

Relevant articles and documents

Cyanate ester resin synthesis method

The invention belongs to the field of synthesis of organic polymers, and particularly relates to a cyanate ester resin synthesis method. According to the method, the cyanogen halide and the bisphenolcompound are dissolved in the same solvent at the same time, and then a triethylamine/isopropanol catalyst is dropwise added into the solvent, so that the reaction time can be shortened, the reactionefficiency can be improved, the use amount of the solvent can be reduced, the problems of dissolution and dropwise addition of the bisphenol compound can be avoided, and the method is also suitable for some indissolvable special phenols. By adopting a triethylamine/isopropanol synthesis system, side reactions can be reduced, and the product purity can be improved. Starting from the dosage ratio ofthe raw materials, the bisphenol compound is excessive, so that the generation of other cyanides in the reaction solution can be avoided, and green production is realized.

Synthesis and characterization of new polynuclear bis-5-oxy-1H-tetrazoles

Different bis-phenols reacted with cyanogen bromide in the presence of triethylamine as base to give the corresponding bis-cyanates which were treated with sodium azide in acetone as solvent to produce new bis(5-oxy-1H-tetrazole) derivatives. One more bis-tetrazole derivative was synthesized by reaction of 5-(4-aminophenoxy)-1H-tetrazole with adipoyl chloride. The prepared compounds were characterized by usual spectroscopic techniques.

Structure of 2,2'-bis(4-cyanatophenyl)isopropylidene

The title compound is monoclinic: a = 13.345(3), b = 11.393(2), c = 10.046(5) Angstroem, β = 108.48(2) deg, Z = 4, P21/c.The structure was determined by direct methods, using MoKα diffractometer data, and refined by full-matrix least squares to R = 0.045 for 1463 reflections.The structure shows a central tetrahedral carbon atom surrounded by two methyl and two phenylcyanate groups.The geometry of the cyanate group compares well with that in 4-chloro-3,5-dimethylphenyl cyanate, the only example of an organic cyanate in the Cambridge Crystallographic data-base (V.3).The intermolecular nitrile, C-H, distances were examined for evidence of a possible dimerization interaction; no significant distances were found.