2574-32-5Relevant articles and documents
Synthesis and spectroscopic studies on some new pentafluorophenylantimony(III and V) derivatives
Saxena,Ranjan, Ashok
, p. 1579 - 1591 (1999)
The oxidative addition reaction of (C6F5)2SbCl with ICl and IN3 yielded (C6F5)2SbI(X)Cl (X = Cl, N3). (C6F5)2SbN3 and (C6F5)2SbCl(NCS)N3 were synthesized by the displacement reactions of (C6F5)2SbCl with NaN3 in the presence of 15-crown-5 or (C6F5)2SbI(N3)Cl with AgNCS, respectively. The reaction of bis(pentafluorophenyl)antimony(V) azido derivatives with PhNCS yielded the corresponding 1,2-cycloaddition products i.e., tetrazole-5-thiones The compounds were characterised by elemental analyses, UV, IR and 19F NMR spectroscopic studies.