2588-79-6

Basic information

• Product Name: 2-Buten-1-amine, N,N,3-trimethyl-
• Synonyms: prenyldimethylamine;dimethyl-(3-methyl-but-2-enyl)-amine;1-Dimethylamino-3-methyl-but-2-en;2-Buten-1-amine,N,N,3-trimethyl;Dimethyl-(3-methyl-but-2-enyl)-amin
• CAS NO: 2588-79-6
• Molecular Formula: C7H15N
• Molecular Weight: 113.203
• Mol File: 2588-79-6.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: 2-Buten-1-amine, N,N,3-trimethyl-(CAS DataBase Reference)
• NIST Chemistry Reference: 2-Buten-1-amine, N,N,3-trimethyl-(2588-79-6)
• EPA Substance Registry System: 2-Buten-1-amine, N,N,3-trimethyl-(2588-79-6)

Safety Data

• Hazardous Substances Data: 2588-79-6(Hazardous Substances Data)

Upstream product

• 4137-10-4 DIMCARB 
• 78-79-5 isoprene 
• 80070-17-3 dimethyl-(3,3-dimethylallyl)-(1-methoxycarbonylethyl)ammonium bromide 

Downstream Products

• 76118-24-6 dimethyl-(3,3-dimethylallyl)-(p-nitrobenzyl)ammonium bromide 
• 107-86-8 3,3-dimethyl acrylaldehyde 
• 41968-30-3 Dimethyl-(3-methyl-1-o-tolyl-but-2-enyl)-amine 
• 41927-48-4 (2,2-Dimethyl-1-phenyl-but-3-enyl)-dimethyl-amine 
• 75713-06-3 3,3-dimethyl-4-dimethylamino-4-phenylhex-1-en-5-yne 
• 75712-96-8 3-dimethylamino-6-methyl-3-phenylhept-1-en-5-yne 
• 23086-38-6 3,3-dimethyl-2-dimethylamino-1-phenylpent-4-en-1-one 
• 76118-16-6 3,3-dimethyl-2-dimethylamino-1-phenylpent-4-en-1-one methiodide 
• 76118-18-8 3,3-dimethyl-2-dimethylamino-1-phenylpentan-1-one 
• 76118-17-7 3,3-dimethyl-1-phenylpent-4-en-1-one 
• 75713-05-2 dimethyl-(3,3-dimethylallyl)-(1-phenylprop-2-ynyl)ammonium bromide 
• 76118-97-3 cinnamyl-(3,3-dimethylallyl)dimethylammonium bromide 
• 41927-43-9 benzyl-dimethyl-(3-methyl-but-2-enyl)-ammonium; chloride 

Relevant articles and documents

Recycling of homogeneous catalysts in reactive ionic liquid-solvent-free aminofunctionalizations of alkenes

The catalyst in homogeneously catalyzed aminofunctionalizations is often difficult to recycle, making these reactions expensive on an industrial scale. The use of dimethylammonium dimethylcarbamate (dimcarb) as a reactive ionic liquid provides an elegant solution to this challenge, as it is a substrate and polar phase at the same time. In this work, homogeneously transition-metal catalyzed reactions-specifically hydroamination, telomerization and hydroaminomethylation-are carried out in neat substrates without additional solvents. The ionic character of dimcarb enables the immobilization of the active catalysts in the reactive ionic liquid, using sulfonated ligands. Investigations regarding the hydroamination of 1,3-dienes led to a total turnover number (TTON) of more than 8700 with β-farnesene in 12 repetitive recycling experiments. The telomerization of 1,3-butadiene was carried out over 30 consecutive runs without any loss of activity, resulting in a TTON of more than 90 000.

INVESTIGATIONS IN THE FIELD OF AMINES AND AMMONIUM COMPOUNDS. CLV. STEVENS REARRANGEMENT WITH THE PARTICIPATION OF A METHYL-SUBSTITUTED ALKOXYCARBONYLMETHYL GROUP

Under the influence of sodium methoxide in ether ammonium salts containing a methyl-substituted alkoxycarbonylmethyl group together with a group of the allylic type undergo a Stevens rearrangement with the formation of the esters of substituted 2-dimethylamino-4-pentenoic acids.The susceptibility to thermal isomerisation in the products from rearrangement of salts containing a γ-phenylallyl or γ,γ-dimethylallyl group as migrating group increases greatly if there is a methyl or allyl substituent in the methoxycarbonylmethyl group.