25983-51-1

Basic information

• Product Name: Benzoic acid, 2,6-bis(phenylmethoxy)-, methyl ester
• Synonyms: Methyl-2.6-dibenzyloxybenzoat;2,6-bis(benzyloxy)benzoic acid methyl ester;2,6-Dibenzyloxy-benzoesaeure-methylester;Benzoic acid,2,6-bis(phenylmethoxy)-,methyl ester;methyl 2,6-dibenzyloxybenzoate
• CAS NO: 25983-51-1
• Molecular Formula: C22H20O4
• Molecular Weight: 348.398
• Mol File: 25983-51-1.mol
• Article Data: 6

Chemical Properties

• CAS DataBase Reference: Benzoic acid, 2,6-bis(phenylmethoxy)-, methyl ester(CAS DataBase Reference)
• NIST Chemistry Reference: Benzoic acid, 2,6-bis(phenylmethoxy)-, methyl ester(25983-51-1)
• EPA Substance Registry System: Benzoic acid, 2,6-bis(phenylmethoxy)-, methyl ester(25983-51-1)

Safety Data

• Hazardous Substances Data: 25983-51-1(Hazardous Substances Data)

Upstream product

• 2150-45-0 methyl 2,6-dihydroxybenzoate 
• 100-39-0 benzyl bromide 
• 303-07-1 2,6-Dihydroxybenzoic acid 

Downstream Products

• 2150-45-0 methyl 2,6-dihydroxybenzoate 
• 138692-79-2 4-[(1Z,4Z,9Z,15Z)-15-(2,6-Bis-benzyloxy-phenyl)-2,8,12,18-tetrahexyl-3,7,13,17-tetramethyl-porphyrin-5-yl]-[1,1';4',1'']terphenyl-4''-carbaldehyde 
• 138536-89-7 4-{4-[(1Z,4Z,9Z,15Z)-15-(2,6-Bis-benzyloxy-phenyl)-2,8,12,18-tetrahexyl-3,7,13,17-tetramethyl-porphyrin-5-yl]-benzyl}-benzaldehyde 
• 138536-88-6 4'-[(1Z,4Z,9Z,15Z)-15-(2,6-Bis-benzyloxy-phenyl)-2,8,12,18-tetrahexyl-3,7,13,17-tetramethyl-porphyrin-5-yl]-biphenyl-4-carbaldehyde 
• 138536-87-5 5-<2,6-bis(benzyloxy)phenyl>-15-(4-formylphenyl)-2,8,12,18-tetrahexyl-3,7,13,17-tetramethylporphine 
• 25983-53-3 3-((3-(benzyloxy)-2-formylphenoxy)methyl)benzene 
• 151322-76-8 methyl 2-trifloxy-6-(benzyloxy)benzoate 
• 74292-74-3 methyl 2-hydroxy-6-(benzyloxy)benzoate 
• 649552-13-6 (3R,1'R)-3-[1'-(imidazolothiocarbonyloxy)butyl]-7-benzyloxyphthalide 
• 649552-15-8 (3S,1'S)-3-[1'-(imidazolothiocarbonyloxy)butyl]-7-benzyloxyphthalide 
• 649552-18-1 (3S,1'S)-3-(1'-hydroxybutyl)-7-benzyloxyphthalide 
• 649552-12-5 (3R,1'R)-3-(1'-hydroxybutyl)-7-benzyloxyphthalide 
• 649552-11-4 methyl 2-(E)-1-pentenyl-6-benzyloxybenzoate 
• 25983-55-5 Methyl 3-benzyloxy-2-formylphenoxyacetat 

Relevant articles and documents

A Concise Total Synthesis of (?)-Berkelic Acid

Reported here is a concise total synthesis of (?)-berkelic acid in eight linear steps. This synthesis features a Catellani reaction/oxa-Michael cascade for the construction of the isochroman scaffold, a one-pot deprotection/spiroacetalization operation for the formation of the tetracyclic core structure, and a late-stage Ni-catalyzed reductive coupling for the introduction of the lateral chain. Notably, four stereocenters are established from a single existing chiral center with excellent stereocontrol during the deprotection/spiroacetalization process. Stereocontrol of the intriguing deprotection/spiroacetalization process is supported by DFT calculations.

Synthesis and absolute configuration of (-)-3-butyl-7-hydroxyphthalide, a cytotoxic metabolite of Penicillium vulpinum.

Both the enantiomers as well as the racemate of 3-butyl-7-hydroxyphthalide (1) were synthesized, and the absolute configuration of the naturally occurring (-)-1 (a weakly cytotoxic metabolite of Penicillium vulpinum) was identified as S.

Synthesis and Fluorescence Properties of Selectively Metallated Diporphyrins with Electron-Accepting Moieties

Synthesis of selectively metallated diporphyrins with electron-accepting moieties is described.Steady-state fluorescence spectra of these compounds showed substantial quenching of the fluorescence of the free-base porphyrin.A possible "superexchange" mechanism of long-range electron transfer is discussed.