26003-39-4

Basic information

• Product Name: N-(4-methylcyclohexyl)formamide
• Synonyms: N-(4-methylcyclohexyl)formamide
• CAS NO: 26003-39-4
• Molecular Weight: 141.213
• Mol File: 26003-39-4.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: N-(4-methylcyclohexyl)formamide(CAS DataBase Reference)
• NIST Chemistry Reference: N-(4-methylcyclohexyl)formamide(26003-39-4)
• EPA Substance Registry System: N-(4-methylcyclohexyl)formamide(26003-39-4)

Safety Data

• Hazardous Substances Data: 26003-39-4(Hazardous Substances Data)

Upstream product

• 32175-00-1 (1R,4R)-1-isocyanato-4-methylcyclohexane 
• 64-18-6 formic acid 
• 33483-65-7 trans-4-methylcyclohexylamine hydrochloride 

Downstream Products

• 25886-43-5 trans-4.N-Dimetil-N-(2.4-dinitrofenil)cicloesilammina 
• 2523-88-8 trans-N,4-dimethylcyclohexylamine 

Relevant articles and documents

Chemoselective Schwartz Reagent Mediated Reduction of Isocyanates to Formamides

Addition of the in situ generated Schwartz reagent to widely available isocyanates constitutes a chemoselective, high-yielding, and versatile approach to the synthesis of variously functionalized formamides. Steric and electronic factors or the presence of sensitive functionalities (esters, nitro groups, nitriles, alkenes) do not compromise the potential of the method. Full preservation of the stereochemical information contained in the starting materials is observed. The use of formamides in the nucleophilic addition of organometallic reagents (Chida-Sato allylation, Charette-Huang addition to imidoyl triflate activated amides, Matteson homologation of boronic esters) is briefly investigated.