26013-17-2

Basic information

• Product Name: (+/-)-N-benzoylmeroquinene methyl ester
• Synonyms: (+/-)-N-benzoylmeroquinene methyl ester
• CAS NO: 26013-17-2
• Molecular Weight: 287.359
• Mol File: 26013-17-2.mol
• Article Data: 8

Chemical Properties

• CAS DataBase Reference: (+/-)-N-benzoylmeroquinene methyl ester(CAS DataBase Reference)
• NIST Chemistry Reference: (+/-)-N-benzoylmeroquinene methyl ester(26013-17-2)
• EPA Substance Registry System: (+/-)-N-benzoylmeroquinene methyl ester(26013-17-2)

Safety Data

• Hazardous Substances Data: 26013-17-2(Hazardous Substances Data)

Upstream product

• 67-56-1 methanol 
• 132240-38-1 {(3S,4S)-1-Benzyl-3-[2-(2-nitro-phenylselanyl)-ethyl]-2-oxo-piperidin-4-yl}-acetic acid tert-butyl ester 
• 117966-09-3 [(3S,4S)-1-Benzyl-3-(2-hydroxy-ethyl)-2-oxo-piperidin-4-yl]-acetic acid tert-butyl ester 
• 132216-36-5 (3S,4S)-4-Methoxycarbonylmethyl-3-vinyl-piperidine-1-carboxylic acid 2,2,2-trichloro-ethyl ester 
• 117966-11-7 ((3S,4S)-1-Benzyl-2-oxo-3-vinyl-piperidin-4-yl)-acetic acid tert-butyl ester 
• 128638-54-0 ((3S,4S)-1-Benzyl-3-vinyl-piperidin-4-yl)-acetic acid tert-butyl ester 
• 128638-52-8 ((3R,4R)-1-Benzyl-3-vinyl-piperidin-4-yl)-acetic acid methyl ester 
• 117966-04-8 Furan-3-carboxylic acid benzyl-(1-methylsulfanyl-vinyl)-amide 
• 117966-08-2 (3aR,7aR)-5-Benzyl-hexahydro-furo[3,2-c]pyridin-4-one 
• 117966-15-1 (3aR,7aR)-5-Benzyl-5,6,7,7a-tetrahydro-3aH-furo[3,2-c]pyridin-4-one 
• 51048-98-7 ((3R,4R)-3-Vinyl-piperidin-4-yl)-acetic acid methyl ester 
• 98-88-4 benzoyl chloride 
• 132240-38-1 {(3S,4R)-1-Benzyl-3-[2-(2-nitro-phenylselanyl)-ethyl]-2-oxo-piperidin-4-yl}-acetic acid tert-butyl ester 
• 117966-09-3 [(3R,4S)-1-Benzyl-3-(2-hydroxy-ethyl)-2-oxo-piperidin-4-yl]-acetic acid tert-butyl ester 

Downstream Products

• 483-03-4 (+/-)-Ajmalicin 

Relevant articles and documents

Photocyclization of enamides. XXXII. Alkaloid synthesis using furopyridone as a synthon: Synthesis of key intermediates for the synthesis of (±)-quinine, (±)-ajmalicine, and (±)-7-demethyltecomanine

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CLAISEN-REARRANGEMENT-MEDIATED RING CONTRACTION OF MACROCYCLIC LACTONES A NEW APPROACH TO CARBOCYCLES AND HETEROCYCLES

Macrocyclic ketene acetals 3 undergo Claisen rearrangements smoothly and constitute a viable and general approach to hetero- or carbocyclic ring systems 4.This novel ring contraction process is subject to high internal asymmetric induction (cf. lactones 7 -> carbocycles 8) as well as relative asymmetric induction in the rearrangements of ketene acetals derived from lactones 18, 23 and 27.Finally, N-benzoylmeroquinene methyl ester (37) was prepared to demonstrate the potential of this methodology in heterocycle synthesis.

1,6-dihydro-3(2H)-pyridinones. VIII. Total synthesis of (±)-corynantheidol and formal synthesis of (±)-quinine

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