260445-02-1Relevant articles and documents
Stereodivergent synthesis of piperidine iminosugars 1-deoxy-D-nojirimycin and 1-deoxy-D-altronojirimycin
De Angelis, Martina,Sappino, Carla,Mandic, Emanuela,D'Alessio, Marianna,De Dominicis, Maria Grazia,Sannino, Sara,Primitivo, Ludovica,Mencarelli, Paolo,Ricelli, Alessandra,Righi, Giuliana
, (2020/12/21)
A stereodivergent approach for producing piperidine iminosugars has been developed employing a common optically active precursor. The key steps of the synthetic pathway are the double diastereoselection in the asymmetric dihydroxylation of the suitable ch
Highly efficient preparation of selectively isotope cluster-labeled long chain fatty acids via two consecutive Csp3-Csp3 cross-coupling reactions
Lethu, Sebastien,Matsuoka, Shigeru,Murata, Michio
supporting information, p. 844 - 847 (2014/03/21)
An efficient synthesis involving two copper-catalyzed alkyl-alkyl coupling reactions has been designed to easily access doubly isotope-labeled fatty acids. Such NMR- and IR-active compounds were obtained in excellent overall yields and will be further used for determining the conformation of an alkyl chain of lipidic biomolecules upon interaction with proteins.
Mechanistic study of the ring-enlargement reaction of (3-oxa-2-silacyclopentyl)methyl radicals into 4-oxa-3-silacyclohexyl radicals. Evidence for a pentavalent silicon-bridging radical transition state in 1,2-rearrangement reactions of β-silyl radicals
Shuto, Satoshi,Sugimoto, Isamu,Abe, Hiroshi,Matsuda, Akira
, p. 1343 - 1351 (2007/10/03)
A mechanistic study was performed on a novel radical ring-enlargement reaction of (3-oxa-2-silacyclopentyl)methyl radicals into 4-oxa-3-silacyclohexyl radicals. Two pathways, one via a pentavalent silicon-bridging radical transition state (or intermediate
