2605-69-8

Basic information

• Product Name: Benzene, pentachloro(trichloromethyl)-
• CAS NO: 2605-69-8
• Molecular Formula: C7Cl8
• Molecular Weight: 367.701
• Mol File: 2605-69-8.mol
• Article Data: 4

Chemical Properties

• CAS DataBase Reference: Benzene, pentachloro(trichloromethyl)-(CAS DataBase Reference)
• NIST Chemistry Reference: Benzene, pentachloro(trichloromethyl)-(2605-69-8)
• EPA Substance Registry System: Benzene, pentachloro(trichloromethyl)-(2605-69-8)

Safety Data

• Hazardous Substances Data: 2605-69-8(Hazardous Substances Data)

Upstream product

• 2136-87-0 2,3,4,5-tetrachloro-1-(trichloromethyl)benzene 
• 21703-93-5 octachlorocycloheptatriene 
• 98-07-7 Benzotrichlorid 
• 608-93-5 pentachlorobenzene 
• 108-88-3 toluene 
• 384-83-8 2,3,4,5,6-pentachloro-1-(trifluoromethyl)benzene 

Downstream Products

• 76570-98-4 cis-perchlorostilbene 
• 52789-10-3 trans-perchlorostilbene 
• 620-83-7 1-methyl-4-(phenylmethyl)benzene 
• 2136-95-0 pentachloro-α,α-dichlorotoluene 
• 2136-78-9 α,α,2,3,4,5,6-pentachlorotoluene 
• 4284-10-0 1-trifluoromethyl-2,4,6-trifluoro-3,5-dichlorobenzene 
• 384-83-8 2,3,4,5,6-pentachloro-1-(trifluoromethyl)benzene 

Relevant articles and documents

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A New Trifluoromethylating Agent: Synthesis of Polychlorinated (Trifluoromethyl)benzenes and 1,3-Bis(trifluoromethyl)benzenes and Conversion into Their Trichloromethyl Counterparts and Molecular Structure of Highly Strained Polychloro-m-xylenes

Mixtures of CCl3F and AlCl3 replace CF3 for H in polychlorobenzenes.Thus, by treatment of a solution of the suitable polychlorobenzene in CCl3F with AlCl3, the following compounds can be prepared: pentachloro- (2), 2,3,4,5-tetrachloro- (5), 2,3,4,6-tetrachloro- (8), 2,3,5,6-tetrachloro- (11), 2,3,4-trichloro- (14), 2,4,5-trichloro- (17), and 2,4,6-trichloro-1-(trifluoromethyl)benzene (20), as well as 4,5,6-trichloro- (31) and 2,4,6-trichloro-1,3-bis(trifluoromethyl)benzene (32).The reaction of the above-mentioned trifluoromethylated compounds with AlCl3 in CS2 yieldstheir trichloromethyl counterparts: 3, 6, 9, 12, 15, 18, 21, 34, and 36.The chlorination of 32 or 36 by means of Silberrad's reagent (SO2Cl2, AlCl3, and S2Cl2) affords perchloro-m-xylene (38), a new highly strained chlorocarbon whose synthesis was attempted repeatedly in the past. 9, 15, 17, and 21, when treated with oleum and then with water, are converted into 2,3,4,6-tetrachloro- (22), 2,3,4-trichloro- (23), 2,4,5-trichloro- (24), and 2,4,6-trichlorobenzoic acid (25), respectively; under similar treatment, 34, 36, and 38 give 4,5,6-trichloro- (33), 2,4,5-trichloro- (35), and tetrachloroisophthalic acid (39), respectively.The formation of the (trifluoromethyl)benzenes is discussed, and in this connection it has been found that CCl3F solutions of 3 and 18 in the presence of AlCl3 give back 2 and 17, respectively.Molecular structures of highly strained m-xylenes 36 and 38, as well as that of the much less strained 34, ascertained by X-ray analysis, are reported and commented.IR, UV, and NMR spectral data of the compounds synthesized are presented.The interesting UV spectrum of 21 is discussed.

DESTRUCTIVE CHLORINATION OF ALKYLBENZENES ON HETEROGENEOUS CATALYSTS.

A study was made of the destructive chlorination of alkylbenzenes in the vapor phase on metal oxides and metal chlorides. This work shows that 380-400 degree C, 11-12 sec contact time, 0. 3-0. 8 mass % MoO//3 on alumina, 7-10% stoichiometric excess of chlorine, and 1:9 toluene/chlorine mole ratio were optimal for the chlorination of toluene to give C//6Cl//6 and CCl//4. The optimal conditions for the preparation of pentachlorobenzyl chloride were 295-320 degree C, 18-22 sec contact time, 1:6 toluene/chlorine mole ratio, and 4-8. 5 mass % MgCl//2 on KSK silica gel. The optimal yields of CCl//4 and C//6Cl//6 were 97. 4-98. 2 and 93. 8-96. 3 mole %, respectively, with 91-93 mole % conversion of chlorine.