26054-65-9

Basic information

• Product Name: (1S,5R,6R,7R)-(-)-2-oxa-6-(hydroxymethyl)-7-acetoxybicyclo<3.3.0>-octan-3-one
• Synonyms: (1S,5R,6R,7R)-(-)-2-oxa-6-(hydroxymethyl)-7-acetoxybicyclo<3.3.0>-octan-3-one
• CAS NO: 26054-65-9
• Molecular Weight: 214.218
• Mol File: 26054-65-9.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: (1S,5R,6R,7R)-(-)-2-oxa-6-(hydroxymethyl)-7-acetoxybicyclo<3.3.0>-octan-3-one(CAS DataBase Reference)
• NIST Chemistry Reference: (1S,5R,6R,7R)-(-)-2-oxa-6-(hydroxymethyl)-7-acetoxybicyclo<3.3.0>-octan-3-one(26054-65-9)
• EPA Substance Registry System: (1S,5R,6R,7R)-(-)-2-oxa-6-(hydroxymethyl)-7-acetoxybicyclo<3.3.0>-octan-3-one(26054-65-9)

Safety Data

• Hazardous Substances Data: 26054-65-9(Hazardous Substances Data)

Usage

Description

(1S,5R,6R,7R)-(-)-2-oxa-6-(hydroxymethyl)-7-acetoxybicyclo<3.3.0>-octan-3-one is a bicyclic compound characterized by a six-membered ring containing oxygen, an acetoxy group, a hydroxymethyl group, and a ketone group. Its specific stereochemistry is indicated by the (1S,5R,6R,7R) prefix, which denotes the arrangement of substituents around the carbon atoms in the structure. This unique configuration may contribute to its potential applications in various industries, particularly the pharmaceutical or chemical sectors.

Uses

Used in Pharmaceutical Industry:
(1S,5R,6R,7R)-(-)-2-oxa-6-(hydroxymethyl)-7-acetoxybicyclo<3.3.0>-octan-3-one is used as a potential pharmaceutical compound for its unique structure and functional groups. The specific stereochemistry and presence of various functional groups may allow it to interact with biological targets or be modified for specific therapeutic purposes.
Used in Chemical Industry:
In the chemical industry, (1S,5R,6R,7R)-(-)-2-oxa-6-(hydroxymethyl)-7-acetoxybicyclo<3.3.0>-octan-3-one may be utilized as a building block or intermediate in the synthesis of more complex molecules. Its unique structure and functional groups could be exploited to create novel chemical entities with specific properties or reactivity.

Upstream product

• 50-00-0 formaldehyd 
• 26054-46-6 (-)-(1S,5R)-2-oxabicyclo[3.3.0]oct-6-en-3-one 
• 64-19-7 acetic acid 
• 90529-18-3 (1SR, 5RS, 6RS, 7RS)-7-acetoxy-6-acetoxymethyl-2-oxabicyclo<3.3.0>octan-3-one 

Downstream Products

• 84786-84-5 Benzoic acid (7S,8R,9S)-9-(tert-butyl-diphenyl-silanyloxymethyl)-8-[(Z)-4-(4-methyl-2,6,7-trioxa-bicyclo[2.2.2]oct-1-yl)-but-2-enyl]-1,4-dithia-spiro[4.4]non-7-yl ester 
• 84786-85-6 C₄₁H₅₀O₆S₂Si 
• 84786-87-8 C₃₁H₃₈O₈S₂ 
• 84786-93-6 C₃₁H₄₀O₈S₃ 
• 84786-88-9 C₃₁H₄₀O₈S₂ 
• 84786-83-4 (7S,8R,9S)-9-(tert-Butyl-diphenyl-silanyloxymethyl)-8-[(Z)-4-(4-methyl-2,6,7-trioxa-bicyclo[2.2.2]oct-1-yl)-but-2-enyl]-1,4-dithia-spiro[4.4]nonan-7-ol 
• 84786-92-5 C₂₅H₃₀O₆S₂ 
• 84786-86-7 C₂₅H₃₂O₆S₂ 
• 84786-81-2 C₂₆H₃₂O₃S₂Si 
• 84800-84-0 C₂₆H₃₄O₃S₂Si 
• 84786-91-4 (3aR,4S,6aS)-4-(tert-Butyl-diphenyl-silanyloxymethyl)-tetrahydro-cyclopenta[b]furan-2,5-dione 
• 70803-92-8 6-[(1R,2R,3S)-2-((Z)-4-Carboxy-but-2-enyl)-3-hydroxy-5-oxo-cyclopentyl]-4-oxo-hexanoic acid 
• 84786-80-1 (3aR,4S,5R,6aS)-hexahydro-5-hydroxy-4-[(tert-butyldiphenylsilyloxy)methyl]-2H-cyclopenta[b]furan-2-one 
• 84786-90-3 Acetic acid (3aR,4S,5R,6aS)-4-(tert-butyl-diphenyl-silanyloxymethyl)-2-oxo-hexahydro-cyclopenta[b]furan-5-yl ester 

Relevant articles and documents

Prins Reaction of 2-Oxabicyclooct-6-en-3-one and Related Derivatives

Reaction of formaldehyde with the title olefinic lactone in acetic acid affords diacetate of 1,3-diol (2a) as the main product in 50-60percent yield via regioselective trans-addition.Less favourable results were obtained with related bicyclic derivatives.