2612-87-5

Basic information

• Product Name: Silane, (2,2-diphenylcyclopropyl)trimethyl-
• CAS NO: 2612-87-5
• Molecular Formula: C18H22Si
• Molecular Weight: 266.458
• Mol File: 2612-87-5.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: Silane, (2,2-diphenylcyclopropyl)trimethyl-(CAS DataBase Reference)
• NIST Chemistry Reference: Silane, (2,2-diphenylcyclopropyl)trimethyl-(2612-87-5)
• EPA Substance Registry System: Silane, (2,2-diphenylcyclopropyl)trimethyl-(2612-87-5)

Safety Data

• Hazardous Substances Data: 2612-87-5(Hazardous Substances Data)

Upstream product

• 75-77-4 chloro-trimethyl-silane 
• 17343-74-7 1,1-dibromo-2,2-diphenylcyclopropane 
• 530-48-3 1,1-Diphenylethylene 
• 18107-18-1 diazomethyl-trimethyl-silane 
• 17873-08-4 (phenylsulfanylmethyl)trimethylsilane 

Relevant articles and documents

Cyclopropylidene Dianion Equivalent. Preparation of 1,1-Dilithio-2,2-diphenylcyclopropane

The title compound was prepared by the treatment of corresponding 1,1-dibromocyclopropane with lithium naphthalene radical anion (Li-C10H8).Trapping of the dilithio compound by chlorotrimethylsilane provided evidence for its highly basic profile which can compete with silylation.

Nucleophilic Addition of Lithiated Phenyl Trimethylsilyl Sulfide to Activated Olefins. A Facile Synthesis of 2-(Functionally) Substituted Silylcyclopropanes

The lithio derivative of phenyl trimethylsilylmethyl sulfide undergoes smooth addition to activated ethylene derivatives to afford trimethylsilylcyclopropanes, except for the addition to methyl 2-phenylpropenoate which leads to the formation of methyl 4-trimethylsilyl-2-phenyl-4-(phenylthio)butanoate.