26131-56-6

Basic information

• Product Name: 3-Methoxythiobenzoic acid O-ethyl ester
• Synonyms: 3-Methoxybenzenecarbothioic acid O-ethyl ester;3-Methoxythiobenzoic acid O-ethyl ester
• CAS NO: 26131-56-6
• Molecular Formula: C₁₀H₁₂O₂S
• Molecular Weight: 196.27
• Mol File: 26131-56-6.mol
• Article Data: 1

Chemical Properties

• Appearance: /
• CAS DataBase Reference: 3-Methoxythiobenzoic acid O-ethyl ester(CAS DataBase Reference)
• NIST Chemistry Reference: 3-Methoxythiobenzoic acid O-ethyl ester(26131-56-6)
• EPA Substance Registry System: 3-Methoxythiobenzoic acid O-ethyl ester(26131-56-6)

Safety Data

• Hazardous Substances Data: 26131-56-6(Hazardous Substances Data)

Upstream product

• 10259-22-0 ethyl 3-methoxybenzoate 

Downstream Products

• 10259-22-0 ethyl 3-methoxybenzoate 
• 133113-67-4 5-Ethoxy-5-(3-methoxy-phenyl)-3-(4-nitro-phenyl)-[1,4,2]dithiazole 
• 619-72-7 4-nitrobenzonitrile 

Relevant articles and documents

Dithiazoles and Related Compounds. Part 3. Preparation of 5H-1,4,2-Dithiazoles via 1,3-Dipolar Cycloadditions between Nitrile Sulphides and Thiocarbonyl Compounds, and some Conversions into 3,5-Diaryl-1,4,2-dithiazolium Salts

Thermolysis of 1,3,4-oxathiazol-2-ones 3 in the presence of thiocarbonyl compounds gives modest to good yields of the little-known 5H-1,4,2-dithiazoles 1, the reaction being successful with diaryl, aryl alkyl and dialkyl ketones, and thiono esters, but failing with dithio esters and tertiary thioamides.The influence of substituents is discussed.Solvolysis of 5-ethoxy-5H-1,4,2-dithiazoles, derived from thiono esters, with perchloric acid in acetic anhydride gives high yields of 3,5-diaryl-1,4,2-dithiazolium salts 9.