261511-22-2

Basic information

• Product Name: (1S)-cis-4-Benzyloxymethylcyclopent-2-en-1-ol
• Synonyms: (1S)-cis-4-Benzyloxymethylcyclopent-2-en-1-ol
• CAS NO: 261511-22-2
• Molecular Weight: 204.269
• Mol File: 261511-22-2.mol
• Article Data: 4

Chemical Properties

• CAS DataBase Reference: (1S)-cis-4-Benzyloxymethylcyclopent-2-en-1-ol(CAS DataBase Reference)
• NIST Chemistry Reference: (1S)-cis-4-Benzyloxymethylcyclopent-2-en-1-ol(261511-22-2)
• EPA Substance Registry System: (1S)-cis-4-Benzyloxymethylcyclopent-2-en-1-ol(261511-22-2)

Safety Data

• Hazardous Substances Data: 261511-22-2(Hazardous Substances Data)

Upstream product

• 100-39-0 benzyl bromide 
• 144938-82-9 (1S,4R)-(+)-4-(Hydroxymethyl)cyclopent-2-enol 
• 267411-96-1 (4S,5R)-3-((1S,2R)-2-Benzyloxymethyl-4-oxo-cyclopentyl)-4,5-diphenyl-oxazolidin-2-one 
• 267411-98-3 (4S,5R)-3-((1S,2S)-2-Benzyloxymethyl-2-ethoxy-4-oxo-cyclopentyl)-4,5-diphenyl-oxazolidin-2-one 
• 1146288-87-0 (1R,2S,4S)-2-(benzyloxymethyl)-4-hydroxycyclopentyl methanesulfonate 
• 39939-07-6 5-(benzyloxymethyl)cyclopentadiene 
• 542-92-7 cyclopenta-1,3-diene 
• 188399-48-6 (1R,2S)-2-((benzyloxy)methyl)cyclopent-3-en-1-ol 

Downstream Products

• 193071-31-7 (1S)-cis-4-Benzyloxymethylcyclopent-2-en-1-yl acetate 
• 267411-97-2 Carbonic acid (1S,4R)-4-benzyloxymethyl-cyclopent-2-enyl ester ethyl ester 
• 1290137-27-7 (1R,2S,4R,5R)-4-(benzyloxymethyl)bicyclo[3.1.0]hexan-2-ol 
• 1146288-96-1 5'-O-benzyl-L-carba-ribothymidine 
• 1290137-21-1 (1S,3S)-3-(benzyloxymethyl)cyclopentanol 
• 1146288-94-9 (1R,2R,3S,4S)-4-(benzyloxymethyl)-2,3-(isopropylidenedioxy)cyclopentanol 
• 1146288-90-5 (1R,4R)-4-(benzyloxymethyl)cyclopent-2-enyl benzoate 
• 1146288-92-7 (1R,2S,3S,4S)-4-(benzyloxymethyl)-2,3-dihydroxycyclopentyl benzoate 
• 1146288-93-8 (1R,2R,3S,4S)-4-(benzyloxymethyl)-2,3-(isopropylidenedioxy)cyclopentyl benzoate 
• 1290137-28-8 C₁₉H₂₂N₂O₃ 
• 1290137-29-9 (1R,2R,4R,5R)-4-(benzyloxymethyl)bicyclo[3.1.0]hexan-2-ol 
• 934986-74-0 (1R,4R)-4-(benzyloxymethyl)cyclopent-2-enol 
• 159163-55-0 9-((1S,4R)-4-Benzyloxymethyl-cyclopent-2-enyl)-6-chloro-9H-purin-2-ylamine 
• 159163-56-1 9-((1S,4R)-4-Benzyloxymethyl-cyclopent-2-enyl)-9H-purin-6-ylamine 

Relevant articles and documents

Synthesis of 2′,3′-modified carbocyclic L -nucleoside analogues

New divergent approaches to 2′,3′-modified carbocyclic L-nucleoside analogues starting from enantiomerically pure (1R,2S)- or (1S,2R)-2-(benzyloxymethyl)cyclopent-3-enol are described. In the key step, stereochemically pure cyclopentanols were condensed with N3-protected thymine through a modified Mitsunobu protocol. Moreover, several routes to different cyclopentanol derivatives, to prepare carbocyclic L-2′,3′-didehydro- 2′,3′-dideoxynucleosides (L-d4N), L-2′,3′- dideoxynucleosides (L-ddN), and L-ribonucleosides are reported. Copyright

Mechanism and applications of lithium amide-induced asymmetric rearrangements of 4-substituted and 4,4-disubstituted cyclopentene oxides to cyclopentenols

The preparation and lithium amide-induced rearrangements of 1,2-dideuterated 4-substituted cyclopentene oxides 11 and 19 are described, providing insight into the deprotonation mechanisms operating in such systems. Highly enantioselective syntheses of 4-substituted cis-4-hydroxymethylcyclopent-2-en-1-ols 32a-c are described. Also described are asymmetric syntheses of prostaglandin precursor 40 and (+)-iridomyrmecin (48) via highly enantioselective rearrangement of the epoxide 3 and subsequent Ireland-Claisen rearrangement. The Royal Society of Chemistry 1999.