26163-45-1

Basic information

• Product Name: Methanone,(3-nitrophenyl)-1-piperidinyl-
• Synonyms: Methanone,(3-nitrophenyl)-1-piperidinyl-;1-(3-nitrobenzoyl)piperidine
• CAS NO: 26163-45-1
• Molecular Formula: C₁₂H₁₄N₂O₃
• Molecular Weight: 234.25116
• Mol File: 26163-45-1.mol
• Article Data: 11

Chemical Properties

• Boiling Point: 402.2°C at 760 mmHg
• Flash Point: 197°C
• Appearance: /
• Density: 1.256g/cm³
• Vapor Pressure: 1.12E-06mmHg at 25°C
• Refractive Index: 1.589
• CAS DataBase Reference: Methanone,(3-nitrophenyl)-1-piperidinyl-(CAS DataBase Reference)
• NIST Chemistry Reference: Methanone,(3-nitrophenyl)-1-piperidinyl-(26163-45-1)
• EPA Substance Registry System: Methanone,(3-nitrophenyl)-1-piperidinyl-(26163-45-1)

Safety Data

• Hazardous Substances Data: 26163-45-1(Hazardous Substances Data)

Usage

InChI:InChI=1/C12H14N2O3/c15-12(13-7-2-1-3-8-13)10-5-4-6-11(9-10)14(16)17/h4-6,9H,1-3,7-8H2

Upstream product

• 110-89-4 piperidine 
• 121-90-4 m-nitrobenzoic acid chloride 
• 74669-56-0 4-(3-Nitrobenzoyloxy)pyridin 
• 99-61-6 3-nitro-benzaldehyde 
• 55118-24-6 pyridin-2-yl 3-nitrobenzoate 
• 197160-09-1 2-chloro-4-nitrophenyl 3-nitrobenzoate 

Relevant articles and documents

METHODS OF CONTROLLING CROP PESTS USING AROMATIC AMIDE INSECT REPELLENTS, METHODS OF MAKING AROMATIC AMIDE INSECT REPELLENTS, AND NOVEL AROMATIC AMIDE INSECT REPELLENTS

Methods of protecting fruit crops from flying insect pests and of repelling flying insects using aromatic amide compounds are disclosed. The methods apply the compounds to various surfaces, such as the fruit crops, the ground or structures adjacent to the fruit crops, or an object, article, human skin or animal. The compounds have the formula RxC6Hy—C(═O)—N(Cy), where RxC6Hy is a substituted phenyl group, each R group is independently C1-C6 alkyl, substituted C1-C4 alkyl, (substituted) C6-C10 aryl, C1-C4 alkoxy, C6-C10 aryloxy, halogen, nitro, cyano, cyanate, isocyanate, nitroso, C1-C4 alkylthio, phenylthio, (halogen-substituted) C1-C4 alkylsulfonyl, phenylsulfonyl, tolylsulfonyl, amino, mono- or di-C1-C4 alkylamino, diphenylamino, di-C1-C4 alkylamido, formyl, C2-C7 acyl, or C1-C6 alkoxycarbonyl; x is an integer of 1 to 5; x+y=5; Cy is a C2-C8 (substituted) alkadiyl, a C4-C6 (substituted) alkenediyl, or a (substituted) diyl of the formula —(CH2CH2)—O—(CH2CH2)—, —(CH2CH2)—NR′—(CH2CH2)— or —(CH2CH2)—S—(CH2CH2)— that, along with the amide N atom, forms a non-aromatic cyclic group; and R′ is C1-C6 alkyl, substituted C1-C4 alkyl, (substituted) C6-C10 aryl, or (substituted) benzyl.

Supported cobalt oxide nanoparticles as efficient catalyst in esterification and amidation reactions

Co/SBA-15 nanoparticle catalysts (CoNP) were prepared using a commonly adapted synthetic route and then utilised for esterification and amidation reactions using aromatic and linear chain compounds for the production of long chain esters and amides. The study shows that the use of CoNP catalysts favours the use of aromatic reactants with electron donating substituents specifically in the para position. For the amidation reaction, good to excellent yields were obtained demonstrating tolerance towards differently substituted aromatic compounds. Overall, the synthesized catalysts proved to be efficient and highly versatile, and recyclable under the investigated conditions.

Metal-free one-pot synthesis of amides using graphene oxide as an efficient catalyst

Graphene oxide (GO), exhibiting a high degree of oxygen functionality and various structural defects, was found to be a highly efficient and cost effective carbocatalyst for the one-pot base-free synthesis of amides from aromatic aldehydes and secondary amine. The chemical and structural features of GO, as probed by FTIR, Raman, XRD and HRTEM analyses, were discussed to understand the catalytic mechanism for the synthesis of amides. The present method obviates the use of transition metal catalysts and needs shorter reaction time. This journal is