262280-87-5

Basic information

• Product Name: manganese(III) 5,10,15-tris(pentafluorophenyl)corrolate
• Synonyms: manganese(III) 5,10,15-tris(pentafluorophenyl)corrolate
• CAS NO: 262280-87-5
• Molecular Weight: 851.435
• Mol File: 262280-87-5.mol
• Article Data: 15

Chemical Properties

• CAS DataBase Reference: manganese(III) 5,10,15-tris(pentafluorophenyl)corrolate(CAS DataBase Reference)
• NIST Chemistry Reference: manganese(III) 5,10,15-tris(pentafluorophenyl)corrolate(262280-87-5)
• EPA Substance Registry System: manganese(III) 5,10,15-tris(pentafluorophenyl)corrolate(262280-87-5)

Safety Data

• Hazardous Substances Data: 262280-87-5(Hazardous Substances Data)

Upstream product

• 1266593-37-6 5,10,15-tris(pentafluorophenyl)corrole 
• 918776-48-4 [(5,10,15-tris(pentafluorophenyl)corrole)Mn(N-p-toluenesulfonate)] 
• 6156-78-1 manganese (II) acetate tetrahydrate 
• 238402-21-6 5,10,15-tris(2,3,4,5,6-pentafluorophenyl)corrole 
• 1291-47-0 1,1'-dimethylferrocene 
• 325462-39-3 5,10,15-tris(pentafluorophenyl)corrolato(oxo)manganese(V) 
• 918776-48-4 (5,10,15-tris(pentafluorophenyl)corrole^(3-))Mn(V)=NTs 
• 488090-78-4 5,10,15-tris(pentafluorophenyl)corrole manganese(V) (N-2,4,6-trichlorophenyl) 
• 2622-14-2 tricyclohexylphosphine 
• 603-35-0 triphenylphosphine 

Downstream Products

• 356042-09-6 2,3,7,8,12,13,17,18-octabromo-5,10,15-tris(pentafluorophenyl)corrolato-manganese(III) 
• 325462-39-3 5,10,15-tris(pentafluorophenyl)corrolato(oxo)manganese(V) 
• 952741-58-1 [(5,10,15-tris(pentafluorophenyl)corrole)Mn^IV]⁺ 
• 325462-39-3 5,10,15-tris(pentafluorophenyl)corrole Mn(V)-oxo 
• 918776-48-4 [(5,10,15-tris(pentafluorophenyl)corrole)Mn(N-p-toluenesulfonate)] 
• 356042-05-2 chloromanganese(IV) 5,10,15-tris(pentafluorophenyl)corrolate 
• 356042-09-6 manganese(III) 5,10,15-tris(pentafluorophenyl)perbromocorrolate 
• 325462-39-3 (5,10,15-tris(pentafluorophenyl)corrole)Mn^V(O) 
• 852529-59-0 Mn(tris(pentafluorophenyl)corrole^(3-))(N-2,6-Cl₂C₆H₃) 
• 488090-77-3 5,10,15-tris(pentafluorophenyl)corrole manganese(V) (N-mesityl) 
• 488090-78-4 5,10,15-tris(pentafluorophenyl)corrole manganese(V) (N-2,4,6-trichlorophenyl) 

Relevant articles and documents

Valence Tautomerization of High-Valent Manganese(V)-Oxo Corrole Induced by Protonation of the Oxo Ligand

The addition of an organic acid to the manganese(V)-oxo corrole complex (tpfc)MnV(O) (tpfc = 5,10,15-tris(pentafluorophenyl)corrole) induces valence tautomerization resulting in the formation of (tpfc+?)MnIV(OH) in acetoni

Visible-light photolysis of corrole-manganese(IV) nitrites to generate corrole-manganese(V)-oxo complexes

Photolysis of highly photo-labile corrole-manganese(IV) nitrites by visible light was studied in three corrole systems with different electronic environments. As observed in all three systems, homolytic cleavage of O–N bond of nitrite ligand resulted in one-electron photo-oxidation to generate manganese(V)-oxo corroles, as determined by their distinct UV–vis spectra and kinetic behaviors. The spectral and kinetic results are rationalized by a multiple oxidation model, where the electron-demand MnV-oxo species may serve as direct two-electron oxidant for oxygen atom transfer reactions and less electron-demand systems undergo a disproportionation reaction to form a putative manganese(VI)-oxo corrole as the true oxidant.

Oxygen atom transfer reactions from sterically encumbered brominated (oxo)manganese(V) corroles to styrene

Seven A3-And trans-A2B manganese(III) corroles (1-7-Mn) differing widely in their electronic and steric features were synthesized and transformed to their corresponding β-brominated manganese(III) corroles derivatives (1a-7a-Mn). Their corresponding (oxo)