262844-00-8

Basic information

• Product Name: methyl (2R,3S)-2-O-t-butyldimethylsilyl-3-O-formyl-2,3-dihydroxy-3-phenylpropionate
• Synonyms: methyl (2R,3S)-2-O-t-butyldimethylsilyl-3-O-formyl-2,3-dihydroxy-3-phenylpropionate
• CAS NO: 262844-00-8
• Molecular Weight: 338.476
• Mol File: 262844-00-8.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: methyl (2R,3S)-2-O-t-butyldimethylsilyl-3-O-formyl-2,3-dihydroxy-3-phenylpropionate(CAS DataBase Reference)
• NIST Chemistry Reference: methyl (2R,3S)-2-O-t-butyldimethylsilyl-3-O-formyl-2,3-dihydroxy-3-phenylpropionate(262844-00-8)
• EPA Substance Registry System: methyl (2R,3S)-2-O-t-butyldimethylsilyl-3-O-formyl-2,3-dihydroxy-3-phenylpropionate(262844-00-8)

Safety Data

• Hazardous Substances Data: 262844-00-8(Hazardous Substances Data)

Upstream product

• 186581-53-3 diazomethane 
• 220820-69-9 (2S,4R,5S)-4-O-t-butyldimethylsilyl-1,2-O-isopropylidene-1,2,4,5-tetrahydroxy-5-phenylpentan-3-one 

Downstream Products

• 262844-04-2 (2R,3S)-2-[[(1,1-dimethylethyl)dimethylsilyl]oxy]-3-hydroxy-3-phenylpropanoic acid methyl ester 
• 122743-18-4 methyl (2R,3S)-2,3-dihydroxy-3-phenylpropanoate 

Relevant articles and documents

Aldol reactions with erythrulose derivatives: Stereoselective synthesis of differentially protected syn-α,β-dihydroxy esters

Boron enolates of 1-O-silylated erythrulose 3,4-acetonides prepared with Brown's chloro-dicyclohexylborane/tertiary amine system have been shown to react with achiral aldehydes in a highly stereoselective way to yield a 1,2- syn/1,3-syn stereoisomer. Thro