26311-81-9

Basic information

• Product Name: 1-Chloro-3,4-dimethyl-1-phenyl-2,5-dihydro-1H-germole
• Synonyms: 1-Chloro-3,4-dimethyl-1-phenyl-2,5-dihydro-1H-germole
• CAS NO: 26311-81-9
• Molecular Formula: C₁₂H₁₅ClGe
• Molecular Weight: 267.34
• Mol File: 26311-81-9.mol
• Article Data: 5

Chemical Properties

• Appearance: /
• CAS DataBase Reference: 1-Chloro-3,4-dimethyl-1-phenyl-2,5-dihydro-1H-germole(CAS DataBase Reference)
• NIST Chemistry Reference: 1-Chloro-3,4-dimethyl-1-phenyl-2,5-dihydro-1H-germole(26311-81-9)
• EPA Substance Registry System: 1-Chloro-3,4-dimethyl-1-phenyl-2,5-dihydro-1H-germole(26311-81-9)

Safety Data

• Hazardous Substances Data: 26311-81-9(Hazardous Substances Data)

Upstream product

• 623-73-4 diazoacetic acid ethyl ester 
• 688-73-3 tri-n-butyl-tin hydride 
• 1074-29-9 trichlorophenylgermane 
• 513-81-5 2,3-dimethyl-buta-1,3-diene 
• 7366-24-7 phenyldichlorogermane 
• 7366-22-5 phenylgermanium chloride 
• 32329-21-8 C₆H₅ClGe 
• 32284-98-3 1,1,2,2-tetrachlorodiphenyldigermane 
• 91123-26-1 (C₆H₅)3GeGeCl₂C₆H₅ 
• 91123-27-2 (C₆H₅)3GeGeCl(C₆H₅)Ge(C₆H₅)3 

Downstream Products

• 78240-49-0 (C₆F₅)3Ge(C₆H₅)Ge(CH₂CCH₃)2 
• 994-31-0 chlorotriethylstannane 
• 79411-62-4 C₆H₅(GeC₄H₄(CH₃)2)2C₆H₅ 
• 91123-28-3 (C₆H₅)3Ge(C₆H₅)Ge(CH₂CCH₃)2 

Relevant articles and documents

REACTIONS DE DECHLORHYDRATATION D'ORGANOCHLOROHYDROGERMANES ET -POLYGERMANES

1,8-Diazabicycloundec-7-ene appears to be an efficient dehydrochlorination agent for the organochlorohydrogermanes PhCl2GeH, R2ClGeH (R = Et, Ph).In diluted solutions the intramolecular α-elimination process leads to germylene through germanate

ASSISTANCE NUCLEOPHILE DANS DES REACTIONS D'ORGANO-HALOGENO- ET -HALOGENO-HYDROGERMANES: GERMYLANIONS, GERMYLENES, DERIVES FONCTIONNELS DU GERMANIUM

Substitution reactions of halogermanes under nucleophilic assistance of tertiary amines or diazo derivatives leading readily to various functional derivatives of germanium have been carried out.Dehydrohalogenation of acidic halohydrogemanes under nucleophilic assistance is a useful way to divalent species, and the germylenes formed are stabilized by complexation with the nucleophilic agent.The reactions proceed via intermediate halogermylanions which lead to the formation of more stable germylenes.The transient halogemylanions have been characterized by means of their nuclophilic additions to carbonyl derivatives.Nucleophilic substitutions of halogermanes using these germylanions lead to the formation of polygermanes.

SYNTHESE DE COMPOSES A LIAISON MIVB-MERCURE. PRECURSEURS D'ESPECES MONOVALENTES (GERMYNES), ET BIVALENTES (GERMYLENES), DE RADICAUX CENTROMETALLES ET D'INTERMEDIAIRES

Polynuclear germyl-mercury compounds are obtained from the reaction of organohydrogermanes PhnGeH4-n or digermanes Ph2nGe2H4-n (n = 1, 2) with dialkylmercury R2Hg.Di- or tri-mercurated geminal polygermates thus synthesized generally present a low stability and undergo thermal- or photodecompositions leading to the corresponding monovalent (germynes), divalent (germylenes) or, trivalent (germanium centered radicals) species and also to intermediate biradicals which could be considered as limit forms of germanium doubly-bonded compounds .Such intermediates have been chemically and spectroscopically characterized.Extension of these reactions to the silicon analogs met with difficulties, and thus previously observed differences between silicon and germanium chemistry were confirmed.