2632-83-9Relevant articles and documents
Palladium-Catalyzed β-Elimination of Aminoboranes from (Aminomethylsilyl)boranes Leading to the Formation of Silene Dimers
Ohmura, Toshimichi,Nishiura, Hiroki,Suginome, Michinori
supporting information, p. 4298 - 4304 (2017/11/20)
Silylboronic esters bearing a N,N-dialkylaminomethyl group on the silicon atoms were synthesized and used in palladium-catalyzed reactions. Five silylboronic esters were synthesized through a reaction of the [(N,N-dialkylaminomethyl)diorganosilyl]lithiums
Highly diastereoselective intramolecular Diels-Alder reaction of chiral silatrienes
Coelho, Paulo J.,Blanco, Luis
, p. 2451 - 2456 (2007/10/03)
New Si-chiral 2-silahexa-3,5-dienyl acrylates were prepared in six steps from dichloro(chloromethyl)methylsilane. The EtAlCl2 catalysed intramolecular Diels-Alder reaction of these compounds gave chiral 4-sila-4a,7,8,8a-tetrahydroisochroman-1-ones in good yield. Very good diastereoselectivity was observed for a silatriene bearing a methyl and a 2-methoxyphenyl substituent on the chiral silicon atom.
Fungicidal 1,2,4-triazole derivatives
-
, (2008/06/13)
Silicon-containing 1,2,4-triazoles having broad-spectrum fungicidal activity have been discovered.