26459-52-9

Basic information

• Product Name: 1-(1,1-dimethylethyl)-3-phenoxy-benzene
• Synonyms: 1-(1,1-dimethylethyl)-3-phenoxy-benzene
• CAS NO: 26459-52-9
• Molecular Weight: 226.318
• Mol File: 26459-52-9.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: 1-(1,1-dimethylethyl)-3-phenoxy-benzene(CAS DataBase Reference)
• NIST Chemistry Reference: 1-(1,1-dimethylethyl)-3-phenoxy-benzene(26459-52-9)
• EPA Substance Registry System: 1-(1,1-dimethylethyl)-3-phenoxy-benzene(26459-52-9)

Safety Data

• Hazardous Substances Data: 26459-52-9(Hazardous Substances Data)

Upstream product

• 585-34-2 3-tert-butylphenyol 
• 98-80-6 phenylboronic acid 
• 1098366-91-6 2-(3-tert-butyl-phenoxy)-benzoic acid 
• 108-86-1 bromobenzene 

Relevant articles and documents

URJC-1-MOF as New Heterogeneous Recyclable Catalyst for C-Heteroatom Coupling Reactions

Guillermo Calleja and co-workers from @urjc describe URJC-1-MOF as a new heterogeneous recyclable catalyst for c-heteroatom coupling reactions. The capacity of copper-based URJC-1-MOF as a MOF catalyst in cross-coupling reactions has been evaluated, focusing on the Chan-Lam-Evans arylation-type reactions on amines and alcohols without extra additives or ligands. The extraordinary chemical and structural stability of URJC-1-MOF and its good specific surface, make this material a promising alternative to homogeneous Cu (II) catalysts for cross-coupling reactions. URJC-1-MOF showed a remarkable catalytic activity for cross-coupling C?N and C?O reactions, higher than other heterogeneous and homogeneous copper-based catalyst, such as CuO, HKUST-1, Cu?MOF-74, Cu(OAc)2 and CuSO4?5H2O. Moreover, its easy recovery by simple filtration and reusability in successive runs without any loss of activity and stability, demonstrates the potential of URJC-1-MOF as an alternative catalyst for this kind of reactions in different chemical media of industrial interest.