26514-42-1Relevant articles and documents
Facile synthesis of triarylmethanimine promoted by a lewis acidbase pair: Theoretical and experimental studies
Liu, Yan,Yang, Qiwu,Hao, Dongling,Zhang, Wenqin
, p. 1390 - 1395,6 (2020/09/02)
An efficient method for triarylmethanimine synthesis promoted by a Lewis acidbase pair (AlCl3Et3N) was designed using mechanistic analysis with the aid of density functional theory. A series of triarylmethanimines were successfully prepared under mild con
Silver(I) Ion Mediatied Desulfurization-Condensation of Thiocarbonyl Compounds with Several Nucleophiles
Shibuya, Isao,Taguchi, Yoichi,Tsuchiya, Tohru,Oishi, Akihiro,Katoh, Eisaku
, p. 3048 - 3052 (2007/10/02)
The desulfurization-condensation reaction was investigated in the presence of silver(I) salt for several kinds of thiocarbonyl compounds with nucleophiles.Such thiocarbonyl compounds as 4,4'-bis(dimethylamino)thiobenzophenone, ethylene trithiocarbonate, and N-(thiobenzoyl)morpholine react with malononitrile or other active methylene compounds in the presence of silver trifluoroacetate to afford the corresponding olefinic compounds together with silver sulfide.This reaction of thiocarbonyl compounds with some other nucleophiles such as aniline derivatives and ethylene glycol, has also afforded imines and 1,3-dioxolane derivatives.