26547-29-5

Basic information

• Product Name: Pyrimidine, 2-[(4-methoxyphenyl)thio]-
• CAS NO: 26547-29-5
• Molecular Formula: C11H10N2OS
• Molecular Weight: 218.279
• Mol File: 26547-29-5.mol
• Article Data: 9

Chemical Properties

• CAS DataBase Reference: Pyrimidine, 2-[(4-methoxyphenyl)thio]-(CAS DataBase Reference)
• NIST Chemistry Reference: Pyrimidine, 2-[(4-methoxyphenyl)thio]-(26547-29-5)
• EPA Substance Registry System: Pyrimidine, 2-[(4-methoxyphenyl)thio]-(26547-29-5)

Safety Data

• Hazardous Substances Data: 26547-29-5(Hazardous Substances Data)

Upstream product

• 696-62-8 para-iodoanisole 
• 131242-36-9 2-sulfanylpyrimidine 
• 1722-12-9 2-chloropyrimidine 
• 13139-86-1 4-methoxyphenyl magnesium bromide 
• 89283-87-4 2-thiocyanatopyrimidine 
• 61686-49-5 2-pyrimidylsulfenyl chloride 
• 104-92-7 1-bromo-4-methoxy-benzene 
• 696-63-9 4-Methoxybenzenethiol 

Relevant articles and documents

Copper-free sonogashira coupling reaction using a trans-spanning 1,2-Bis(2-thienylethynyl)benzene ligand

Novel copper-free Sonogashira coupling reaction of aryl halides with terminal acetylenes proceeded in the presence of 1,2-bis(2-thienylethynyl) benzene (1) as a trans-bidentatable ligand.

Coupling of thiols and aromatic halides promoted by diboron derived super electron donors

We have proven that pyridine-boryl complexes can be used as superelectron donors to promote the coupling of thiols and aromatic halides through a SRN1 mechanism. The reaction is efficient for a broad substrate scope, tolerating heterocycles including pyridines, enolizable or reducible functional groups. The method has been applied to intermediates in drug synthesis as well as interesting functionalized polythioethers through a controlled and consecutive intramolecular electron transfer process.

Palladium Nanoparticles Immobilized on Nanosilica Triazine Dendritic Polymer (Pd np -nSTDP) as Catalyst in the Synthesis of Mono-, Di-, and Trisulfides through C-S Cross-Coupling Reactions

A wide variety of diaryl sulfides has been synthesized in excellent yields via C-S cross-couplings of aryl/heteroaryl halides with aromatic/heteroaromatic thiols in the presence of palladium nanoparticles immobilized on nanosilica triazine dendritic polymer (Pd np -nSTDP) as a reusable catalyst under thermal conditions and microwave irradiation. Pd np -nSTDP also showed excellent catalytic activity for the preparation of a series of di- and trisulfides with benzene, pyridine, pyrimidine, and/or 1,3,5-triazine as the central cores by one-pot multi C-S cross-coupling reactions. Georg Thieme Verlag Stuttgart. New York.