26553-51-5Relevant articles and documents
Chemo- and regioselective reductive transposition of allylic alcohol derivatives via iridium or rhodium catalysis
Lundgren, Rylan J.,Thomas, Bryce N.
supporting information, p. 958 - 961 (2016/01/20)
We report highly chemo- and regioselective reductive transpositions of methyl carbonates to furnish olefin products with complementary regioselectivity to that of established Pd-catalysis. These Rh- and Ir-catalysed transformations proceed under mild conditions and enable selective deoxygenation in the presence of functional groups that are susceptible to reduction by metal hydrides.
Base-Induced α-Alkenylation of Ethyl Bromoacetate, Phenacyl Bromide, and Chloroacetonitrile via B-trans -1-Alkenyl-9-borabicyclononanes
Brown, Herbert C.,Bhat, Narayan G.,Campbell, James B.
, p. 3398 - 3400 (2007/10/02)
B-trans-1-Alkenyl-9-borabicyclononanes, easily and quantitatively prepared by the reaction of 9-BBN with various 1-alkynes in tetrahydrofuran, undergo facile reaction with α-halo carbanions generated from ethyl bromoacetate, phenacyl bromide, and c
