26620-08-6Relevant articles and documents
HIGH-COVERAGE, LOW ODOR MALODOR COUNTERACTANT COMPOUNDS AND METHODS OF USE
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Page/Page column 32, (2016/04/20)
The present invention relates to novel compounds and their use as malodor counteractant materials.
Microwave mediated protection of hindered phenols and alcohols
Pothi, Tejas,Dawange, Mahesh,Chavan, Kamlesh,Sharma, Rajiv,Deka, Nabajyoti
, p. 706 - 711 (2013/03/28)
Hindered phenols and alcohols were protected as their corresponding ethers using different alkylating agents in presence of KOH/DMSO under microwave irradiation.
Alkyl- and aryl-oxygen bond activation in solution by rhodium(I), palladium(II), and nickel(II). Transition-metal-based selectivity
Van Der Boom, Milko E.,Liou, Shyh-Yeon,Ben-David, Yehoshoa,Shimon, Linda J. W.,Milstein, David
, p. 6531 - 6541 (2007/10/03)
Reaction of [RhCl(C8H14)2]2 (C8H14 = cyclooctene) with 2 equiv of the aryl methyl ether phosphine 1 in C6D6 results in an unprecedented metal insertion into the strong sp2-sp3 aryl-O bond. This remarkable reaction proceeds even at room temperature and occurs directly, with no intermediacy of C-H activation or insertion into the adjacent weaker ArO-CH3 bond. Two new phenoxy complexes (8 and 9), which are analogous to the product of insertion into the ArO-CH3 bond (had it taken place) were prepared and shown not to be intermediates in the Ar-OCH3 bond cleavage process. Thus, aryl-O bond activation by the nucleophilic Rh(I) is kinetically preferred over activation of the alkyl-O bond. The phenoxy Rh(I)-η1-N2 complex (8) is in equilibrium with the crystallographically characterized Rh(I)-μ-N2-Rh(I) dimer(12). Reaction of [RhClC8H14)2]2 with 2 equiv of the aryl methyl ether phosphine 2, PPh3, and excess HSiR3 (R = OCH2CH3, CH2CH3) results also in selective metal insertion into the aryl-O bond and formation of (CH3O)SiR3. Thus, transfer of a OCH3 group from carbon to silicon was accomplished, showing that hydrosilation of an unstrained aryl-O single bond by a primary silane is possible. The selectivity of C-O bond activation is markedly dependent on the transition-metal complex and the alkyl group involved, allowing direction of the C-O bond activation process at either the aryl-O or alkyl-O bond. Thus, contrary to the reactivity of the rhodium complex, reaction of NiI2 or Pd(CF3CO2)2 with 1 equiv of 1 in ethanol or C6D6 at elevated temperatures results in exclusive activation of the sp3-sp3 ArO-CH3 bond, while reaction of the analogous aryl ethyl ether 4 and Pd(CF3CO2)2 results in both sp3-sp3 and sp2-sp3 C-O bond activation. The resulting phenoxy Pd(II) complex (18) is fully characterized by X-ray analysis. Heating the latter under mild dihydrogen pressure results in hydrodeoxygenation to afford an aryl-Pd(II) complex (19).
