266323-41-5Relevant articles and documents
Thermal transformations of phenyltrichlorogermane in the gas phase
Chernyshev,Komalenkova,Yakovleva,Bykovchenko,Khromykh,Bochkarev,Shcherbinin
, p. 1406 - 1409 (2007/10/03)
Pyrolysis of PhGeCl3 and its mixtures with allyl chloride and isoprene in the temperature range 500-680°C was investigated. PhGeCl3 vigorously decomposes at temperatures higher 600°C, and its decomposition involves both dichlorogermylenes and trichlorogermyl radical. Pyrolysis of mixtures of PhGeCl3 with isoprene or allyl chloride yields respectively trichloro(1,2-dimethyl-2-propenyl)germane, isopentyltrichloro germanes, and 1,1-dichloro-3-methyl-1-germacyclo-3-pentene or allyltrichlorogermane. A mechanism of formation of these products is proposed.