266323-47-1

Basic information

• Product Name: (S)-1-(2-furyl)-1-(4-methoxybenzyloxy)ethane
• Synonyms: (S)-1-(2-furyl)-1-(4-methoxybenzyloxy)ethane
• CAS NO: 266323-47-1
• Molecular Weight: 232.279
• Mol File: 266323-47-1.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: (S)-1-(2-furyl)-1-(4-methoxybenzyloxy)ethane(CAS DataBase Reference)
• NIST Chemistry Reference: (S)-1-(2-furyl)-1-(4-methoxybenzyloxy)ethane(266323-47-1)
• EPA Substance Registry System: (S)-1-(2-furyl)-1-(4-methoxybenzyloxy)ethane(266323-47-1)

Safety Data

• Hazardous Substances Data: 266323-47-1(Hazardous Substances Data)

Upstream product

• 4208-64-4 1-(2-furyl)ethanol 
• 4208-64-4 (S)-1-(2-furanyl)ethanol 
• 824-94-2 p-methoxybenzyl chloride 

Downstream Products

• 266323-53-9 (2S,6S,9E,11R,12S)-6,12-dimethyl-2-(2-furyl)-11-(methoxymethoxy)-14-(4-methoxyphenyl)-3,7,13-trioxa-9-tetradecene-4,8-dione 
• 266323-51-7 (2S,6S,9E,12S)-6,12-dimethyl-2-(2-furyl)-14-(4-methoxyphenyl)-3,7,13-trioxa-9-tetradecene-4,8,11-trione 
• 266323-52-8 (2S,6S,9E,11R,12S)-6,12-dimethyl-2-(2-furyl)-11-hydroxy-14-(4-methoxyphenyl)-3,7,13-trioxa-9-tetradecene-4,8-dione 
• 266323-48-2 (2E,5S)-5-(4-methoxybenzyloxy)-4-oxo-2-hexenoic acid 
• 172923-77-2 (+)-macrosphelide A 
• 266323-59-5 (2E,5S)-5-(4-methoxybenzyloxy)-4-oxo-2-hexenal 

Relevant articles and documents

Total synthesis of macrosphelides B and A

An efficient total synthesis of macrosphelide B has been developed in which the C(5)-O(10) and the C(11)-O(16) fragments were prepared from (S)-1- (2-furyl)ethanol of >98% ee via oxidation of the furan part. In addition, macrosphelide B was transformed stereoselectively into macrosphelide A by reduction followed by Mitsunobu inversion. (C) 2000 Elsevier Science Ltd.