2666-65-1Relevant articles and documents
Synthetic method of N-dichloromethylene aniline derivative
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Paragraph 0039; 0040; 0041; 0042, (2017/08/27)
The invention discloses a synthetic method of an N-dichloromethylene aniline derivative represented by the formula II, wherein the synthesis method comprises the steps: with an isonitrile compound represented by the formula I as a raw material, in an organic solvent and under an action of iodobenzene dichloride represented by the formula III, carrying out a stirring reaction at the temperature of 0-50 DEG for 0.5-5 hours, and after the reaction is finished, separating and purifying the reaction liquid to obtain the N-dichloromethylene aniline derivative represented by the formula II. The synthetic method has the advantages of small toxicity of a chlorine source, environmental friendliness, mild reaction conditions, good universality of functional groups, convenience in operation and the like.
Methyl n-aryl-n-formyldithiocarbamates and fluorination thereof
Petko,Yagupol'skii
, p. 1173 - 1177 (2007/10/03)
By reaction of unsubstituted and substituted in the benzene ring formanilides with carbon disulfide and potassium hydroxide in dimethylformamide followed by methylation with methyl iodide were prepared methyl N-aryl-N-formyldithiocarbamates. The reaction of methyl N-4-bromophenyl-N-formyldithiocarbamate with SF4 furnished 4-bromo-N-difluorornethyl-N-trifluoromethylaniline.